FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2032334287> ?p ?o ?g. }

• W2032334287 endingPage "44" @default.
• W2032334287 startingPage "35" @default.
• W2032334287 abstract "Pd membranes are often used to remove the H2 produced in dehydrogenation reactions, thereby relieving the equilibrium limitations on the product yield. These processes, however, can still be limited by the slow kinetics of the dehydrogenation reaction. If O2 is added to the system, the reaction proceeds through both the very fast oxidative dehydrogenation route as well as the dehydrogenation route. Thus, the addition of O2 can suppress a kinetic limitation, while the removal of H2 through the Pd membrane can alleviate the equilibrium limitation imposed on the system by the dehydrogenation route. In this study, we have examined the oxidative dehydrogenation of isobutane in a Pd membrane reactor over Pt/α-Al2O3 and Rh/α-Al2O3 monoliths and Pt/γ-Al2O3 pellets. We have examined iC4H10 : O2 ratios of 1.0 to 2.0, resulting in operating temperatures ranging from 400 to 700°C. While most of this heat is generated by the exothermicity of the reaction, some additional heating was used to boost conversions. Typical contact times ranged from 0.04 to 0.25 s. By continuously removing the H2 produced, isobutylene yields increased. Yield improvements depended strongly on the balance of reaction time with H2 removal time and the importance of the dehydrogenation in the overall reaction scheme." @default.
• W2032334287 created "2016-06-24" @default.
• W2032334287 creator A5075594838 @default.
• W2032334287 creator A5091080242 @default.
• W2032334287 date "2000-02-01" @default.
• W2032334287 modified "2023-10-12" @default.
• W2032334287 title "Oxidation of isobutane over supported noble metal catalysts in a palladium membrane reactor" @default.
• W2032334287 cites W1642427618 @default.
• W2032334287 cites W1814345486 @default.
• W2032334287 cites W1968019409 @default.
• W2032334287 cites W1968756817 @default.
• W2032334287 cites W1972455675 @default.
• W2032334287 cites W1973322188 @default.
• W2032334287 cites W1973465518 @default.
• W2032334287 cites W1975829402 @default.
• W2032334287 cites W1986710413 @default.
• W2032334287 cites W1992028896 @default.
• W2032334287 cites W1996115000 @default.
• W2032334287 cites W1998827999 @default.
• W2032334287 cites W2010121364 @default.
• W2032334287 cites W2013047419 @default.
• W2032334287 cites W2018092100 @default.
• W2032334287 cites W2029001724 @default.
• W2032334287 cites W2037427224 @default.
• W2032334287 cites W2047834333 @default.
• W2032334287 cites W2049382386 @default.
• W2032334287 cites W2065926062 @default.
• W2032334287 cites W2067004721 @default.
• W2032334287 cites W2067231934 @default.
• W2032334287 cites W2081216654 @default.
• W2032334287 cites W2082938696 @default.
• W2032334287 cites W2084226646 @default.
• W2032334287 cites W2086776435 @default.
• W2032334287 cites W2088880680 @default.
• W2032334287 cites W2092260921 @default.
• W2032334287 cites W2136733582 @default.
• W2032334287 cites W2152010918 @default.
• W2032334287 doi "https://doi.org/10.1016/s0920-5861(99)00260-6" @default.
• W2032334287 hasPublicationYear "2000" @default.
• W2032334287 type Work @default.
• W2032334287 sameAs 2032334287 @default.
• W2032334287 citedByCount "21" @default.
• W2032334287 countsByYear W20323342872013 @default.
• W2032334287 countsByYear W20323342872014 @default.
• W2032334287 countsByYear W20323342872022 @default.
• W2032334287 crossrefType "journal-article" @default.
• W2032334287 hasAuthorship W2032334287A5075594838 @default.
• W2032334287 hasAuthorship W2032334287A5091080242 @default.
• W2032334287 hasConcept C119889771 @default.
• W2032334287 hasConcept C127413603 @default.
• W2032334287 hasConcept C134121241 @default.
• W2032334287 hasConcept C15920480 @default.
• W2032334287 hasConcept C161790260 @default.
• W2032334287 hasConcept C178790620 @default.
• W2032334287 hasConcept C179104552 @default.
• W2032334287 hasConcept C185592680 @default.
• W2032334287 hasConcept C191897082 @default.
• W2032334287 hasConcept C192562407 @default.
• W2032334287 hasConcept C2775871042 @default.
• W2032334287 hasConcept C2776906966 @default.
• W2032334287 hasConcept C2778861962 @default.
• W2032334287 hasConcept C42360764 @default.
• W2032334287 hasConcept C502130503 @default.
• W2032334287 hasConcept C521977710 @default.
• W2032334287 hasConcept C75473681 @default.
• W2032334287 hasConcept C97488330 @default.
• W2032334287 hasConceptScore W2032334287C119889771 @default.
• W2032334287 hasConceptScore W2032334287C127413603 @default.
• W2032334287 hasConceptScore W2032334287C134121241 @default.
• W2032334287 hasConceptScore W2032334287C15920480 @default.
• W2032334287 hasConceptScore W2032334287C161790260 @default.
• W2032334287 hasConceptScore W2032334287C178790620 @default.
• W2032334287 hasConceptScore W2032334287C179104552 @default.
• W2032334287 hasConceptScore W2032334287C185592680 @default.
• W2032334287 hasConceptScore W2032334287C191897082 @default.
• W2032334287 hasConceptScore W2032334287C192562407 @default.
• W2032334287 hasConceptScore W2032334287C2775871042 @default.
• W2032334287 hasConceptScore W2032334287C2776906966 @default.
• W2032334287 hasConceptScore W2032334287C2778861962 @default.
• W2032334287 hasConceptScore W2032334287C42360764 @default.
• W2032334287 hasConceptScore W2032334287C502130503 @default.
• W2032334287 hasConceptScore W2032334287C521977710 @default.
• W2032334287 hasConceptScore W2032334287C75473681 @default.
• W2032334287 hasConceptScore W2032334287C97488330 @default.
• W2032334287 hasIssue "1-3" @default.
• W2032334287 hasLocation W20323342871 @default.
• W2032334287 hasOpenAccess W2032334287 @default.
• W2032334287 hasPrimaryLocation W20323342871 @default.
• W2032334287 hasRelatedWork W176657073 @default.
• W2032334287 hasRelatedWork W1814345486 @default.
• W2032334287 hasRelatedWork W2004779448 @default.
• W2032334287 hasRelatedWork W2351531212 @default.
• W2032334287 hasRelatedWork W2375414431 @default.
• W2032334287 hasRelatedWork W2375778746 @default.
• W2032334287 hasRelatedWork W2775523334 @default.
• W2032334287 hasRelatedWork W2782080762 @default.
• W2032334287 hasRelatedWork W2913323887 @default.
• W2032334287 hasRelatedWork W3041273743 @default.

• next