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- W2032337701 abstract "Abstract A series of photoactive complexes of [Ru II bis(bipyridyl){2‐(4‐methylpyridin‐2‐yl)benzo[ d ]‐X‐azole}](PF 6 ) 2 (X = N–CH 3 , 1 ; S, 2 ; or O, 3 ) have been synthesized and fully characterized by proton and 13 C NMR spectroscopy and UV/Vis spectroscopy. The X‐ray structure of 1 is also reported. The electrochemical behavior and the photophysical properties of 1 – 3 have been investigated. Cyclic voltammetry (CV) reveals the presence of three consecutive one‐electron reduction processes and a single one‐electron oxidation process that are chemically and electrochemically reversible. In all cases, electrogenerated chemiluminescence (ECL) has been observed in the presence of the co‐reactant tri‐ n ‐propylamine (TPA). An analogue of 1 has been synthesized, [Ru II bis(bipyridyl){2‐(4‐methylpyridin‐2‐yl)benzo[ d ]‐X‐azole}](PF 6 ) 2 [X = N(CH 2 ) 5 CO 2 H, 4 ], it has been coupled with bovine serum albumin (BSA), and its photophysical properties investigated. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)" @default.
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- W2032337701 date "2006-07-01" @default.
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- W2032337701 title "Synthesis, Electrochemical and Electrogenerated Chemiluminescence Studies of Ruthenium(II) Bis(2,2′‐bipyridyl){2‐(4‐methylpyridin‐2‐yl)benzo[<i>d</i>]‐X‐azole} Complexes" @default.
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- W2032337701 doi "https://doi.org/10.1002/ejic.200600099" @default.
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