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• W2032347908 abstract "We present a study of the use of chloro-functionalized mesoporous silicas as supports for immobilization of Au(III) Schiff base complex, and use of this composite material as heterogeneous catalyst for homocoupling of aryl boronic acid. The catalyst was characterised by XRD, FTIR, UV–vis DRS, TG-DTA, etc. Catalyst was initially tested using the coupling of phenylboronic acid with bromo benzene in the presence of K2CO3 and with xylene as solvent. The reaction was also tested in the absence of the aryl halide and K2CO3. The results indicate that in our catalytic system base is not needed for the activation of phenylboronic acid, and its only role is to neutralize the boric acid. The optimized catalysts are also active in the coupling of a range of aryl boronic acids, and after four catalytic runs they show virtually no drop in activity." @default.
• W2032347908 created "2016-06-24" @default.
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• W2032347908 date "2011-06-01" @default.
• W2032347908 modified "2023-10-14" @default.
• W2032347908 title "A fascinating Suzuki homo-coupling reaction over anchored gold Schiff base complexes on mesoporous host" @default.
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• W2032347908 doi "https://doi.org/10.1016/j.molcata.2011.04.002" @default.
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