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- W2032362823 abstract "A convenient method for the α-alkylation of (S)-asparagine with “self-regeneration of the stereogenic center” is described. The synthetic protocol involves stereoselective conversion of (S)-asparagine into enantiopure imino ether (2S,6S)-9, which is then alkylated with complete diastereoselectivity to give trans products 10−13 in good yields. Hydrolysis of these alkylated heterocycles is accomplished under mild acidic conditions to give the desired, enantiopure α-alkyl aspartic acids in excellent yields." @default.
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- W2032362823 date "1998-06-23" @default.
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- W2032362823 title "α-Alkylation of (<i>S</i>)-Asparagine with Self-Regeneration of the Stereogenic Center: Enantioselective Synthesis of α-Substituted Aspartic Acids<sup>1</sup><sup>,</sup><sup>2</sup>" @default.
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- W2032362823 doi "https://doi.org/10.1021/jo980367a" @default.
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