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• W2032439890 abstract "A wide range of bimetallic aluminum molecules are formed in combinations between Salen Schiff base ligands and either AlR3 or AlR2Cl. They are of the general formulas L(AlR2)2 and L(AlRCl)2 with R = alkyl and L = Salen(tBu) ligand with relatively unusual “backbone” connections between the nitrogen atoms, 1,2-cyclohexylene (Salcen(tBu)), 1,4-butylene (Salben(tBu)), 1,5-pentylene (Salpten(tBu)), 1,6-hexylene (Salhen(tBu)), and 1,4-phenylene (1,4-Salophen(tBu)). Additionally, previously unknown ligands were employed with the “backbones” 1,4-bis(p-aminobenzyl)benzene (Salmaben(tBu)), 1-(m-aminobenzoyl)-4-(m-aminobenzyl)benzene (Salmabmaben(tBu)), and 4,4‘-bis(m-aminobenzoyl)diphenylmethane (Salmadmen(tBu)). The ligands for these compounds were designed to feature two group 13 sites at long and varying distances from one another. The compounds were characterized by mp analyses, IR, and 1H NMR, and X-ray structures were determined for the examples R,R‘-Salcen(tBu){AlMe2}2 (1), Salben(tBu){AlMe2}2 (2), 1,4-Salophen(tBu){GaEt2}2 (7), R,R‘-Salcen(tBu){AlMeCl}2 (11), Salben(tBu){AlMeCl}2 (13), and Salhen(tBu){AlMeCl}2 (14)." @default.
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• W2032439890 date "2000-03-30" @default.
• W2032439890 modified "2023-09-27" @default.
• W2032439890 title "Bimetallic Aluminum and Gallium Chelates with N₂O₂ Ligands" @default.
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• W2032439890 doi "https://doi.org/10.1021/om990829q" @default.
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