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- W2032455762 abstract "The magnetic properties of the compounds R2Cr2C3 (R = Y, Gd-Lu) with Ho2Cr2C3-type structure were determined between 2 and 300 K with a SQUID magnetometer at magnetic flux densities up to 5.5 T. The chromium atoms of these carbides do not carry magnetic moments as is shown by the Pauli paramagnetism of the yttrium and lutetium compound. The others show Curie-Weiss behaviour, The magnetic moments of most of these carbides are slightly below those expected for the free R3+ ions. For the ytterbium compound the experimental moment μexp = 3.5(3) μB is considerably lower than that of the Yb3+ ion of μeff = 4.54μB suggesting mixed valence of the ytterbium atoms. The carbides R2Cr2C3 with R = Gd-Tm order antiferromagnetically and the Néel temperatures follow the de Gennes function with a slight deviation for the terbium compound. The magnetization behaviour of the four carbides with R = Tb-Er suggests metamagnetism. Yb2Cr2C3 is a new compound which was prepared in a lithium flux from the elemental components." @default.
- W2032455762 created "2016-06-24" @default.
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- W2032455762 date "1993-02-01" @default.
- W2032455762 modified "2023-10-16" @default.
- W2032455762 title "Preparation of Yb2Cr2C3 and magnetic properties of the carbides R2Cr2C3 (R = Y, Gd-Lu) with Ho2Cr2C3-type structure" @default.
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- W2032455762 doi "https://doi.org/10.1016/0022-3697(93)90317-k" @default.
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