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- W2032509315 abstract "Green and blue ultramarine pigments are characterized by the sodalite structure Na(6)(Al(6)Si(6)O(24)) and colored inserted species. These chromophores are sulfur species: S(3)(-) (blue) and S(2)(-) (yellow). Both radicals are encapsulated inside the β-cages. They contribute to the EPR spectrum of ultramarine pigments. The well-known strong EPR signal observed in all ultramarine pigments Continuous-Wave (CW) spectra has long been assigned to S(3)(-) (g = 2.029). In contrast, the S(2)(-) contribution is still subject to controversy because its signal in ultramarine pigments was not resolved even at low temperature in CW-EPR experiments. In this study, we identify unambiguously for the first time by CW-EPR and field sweep-echo detected (FS-ED) EPR the signal of S(2)(-) in ultramarine pigments and we determine its tensor components: g(1) = 2.69(6), g(2) = 2.03(4) and g(3) = 1.86(4)." @default.
- W2032509315 created "2016-06-24" @default.
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- W2032509315 date "2011-01-01" @default.
- W2032509315 modified "2023-10-16" @default.
- W2032509315 title "Identification of the EPR signal of S2− in green ultramarine pigments" @default.
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- W2032509315 doi "https://doi.org/10.1039/c0cp02970j" @default.
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