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- W2032544601 abstract "By the study of 3000 kinetic runs for all homogeneous two-step models under variation of activation and signal parameters, it has been stated that the generated Mechanistic Concentration Code (=MCC) is the best vehicle for data extraction in Thermal Analysis. It summarises the rate-controlling steps and their molecularities, independently of their activation data and (to 80–90%) of their method-specific signal parameters. Hence, an optimum evaluation needs the internal (best-fitted) reference step, the initial concentration of a reference reactant, and equal weight of theoretical and experimental results, reached using the same algorithms. Thus, the MCC of any series measured in general allows for a reliable model determination via the distribution into all two-step models, using the tools of probability and decision theory. A transfer of the strategy to heterogeneous reactions is discussed." @default.
- W2032544601 created "2016-06-24" @default.
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- W2032544601 date "1992-03-01" @default.
- W2032544601 modified "2023-10-16" @default.
- W2032544601 title "Experimentally available kinetic codes as a tool for promising data extraction in thermal analysis" @default.
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- W2032544601 doi "https://doi.org/10.1007/bf01915493" @default.
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