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- W2032545403 abstract "The complex formation and dehydration processes in the system M(CH3COO)2CH3OHH2O have been studied by the methods of the physico-chemical analysis at 25°C; (M = Mg2+, Ca2+ and Ba2+). In the Mg(CH3COO)2CH3OHH2O system. methanol was found to behave as a solvent in which complex formation reactions take place, including also methanolation of Mg2+. The fields of equilibrium existence of two new compounds have been found: Mg(CH3COO)2 · 3H2O · CH3OH and Mg(CH3COO)2 · 1,5 CH3OH. In the systems M(CH3COO)2CH3OHH2O (M = Ca2+, Ba2+), methanol was found to react as a dehydrating reagent. Gleichgewichtsuntersuchungen im System M(CH3COO)2CH3OHH2O (Me = Mg2+, Ca2+, Ba2+) bei 25°C Die Komplexbildungs- und Dehydratationsvorgänge im System M(CH3COO)2CH3OHH2O (Me = Mg2+, Ca2+, Ba2+) wurden bei 25°C untersucht. Das Methanol kann im System Mg(CH3COO)2CH3OHH2O als Lösungsmittel, in welchem Komplexbildungserscheinungen stattfinden, betrachtet werden, und zwar tritt eine Solvatation der Magnesiumionen mit Methanol ein. Die Kristallisationsfelder von zwei neuen, bisher in der Literatur unbekannten Verbindungen sind festgestellt worden, nämlich Mg(CH3COO)2 · 3 H2O · CH3OH und Mg(CH3COO)2 · 1,5 CH3OH. In den Systemen M(CH3COO)2CH3OHH2O (M = Ca2+, Ba2+) übt das Methanol nur eine Dehydratationswirkung aus." @default.
- W2032545403 created "2016-06-24" @default.
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- W2032545403 date "1983-02-01" @default.
- W2032545403 modified "2023-09-24" @default.
- W2032545403 title "Study on the equilibrium in the M(CH3 COO)2 CH3 OH H2 O system (M Mg2+ , Ca2+ , Ba2+ ) at 25°C" @default.
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- W2032545403 doi "https://doi.org/10.1002/zaac.19834970223" @default.
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