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- W2032597966 abstract "Gibbs free energies of solute—solvent interactions and the Gibbs free energies of transfer for salicylic, sulphosalicylic and sulphanilic acids from water to ethanol, N-methypyrollidone, acetonitrile, N,N-dimethylformamide, dimethylsulphoxide, propylene carbonate and N-methylformamide were calculated from the measured solubility data at 25°C. K (association), ΔG (electrostatic) and ΔG (neutral) were theoretically calculated for the three acids used. It is found that the ΔG of interaction and K values of salicylic acid are larger than those of sulphosalicylic and sulphanilic acids in the organic solvents used. This behaviour is due to both inter- and intramolecular interactions of the hydroxyl and carboxylic groups of salicylic acid with the solvent dipoles." @default.
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- W2032597966 date "1985-04-01" @default.
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- W2032597966 title "Gibbs free energies of solute—solvent interactions for salicylic, sulphosalicylic and sulphanilic acids in various solvents" @default.
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- W2032597966 doi "https://doi.org/10.1016/0040-6031(85)87064-7" @default.
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