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• W2032656075 endingPage "9548" @default.
• W2032656075 startingPage "9543" @default.
• W2032656075 abstract "The reactions of the stable β-diketiminate tin(II) hydride LSnH [L = HC(CMeNAr)2, Ar = 2,6-iPr2C6H3] with different ketones (Ph2CO, 2-Py2CO, cyPr2CO, and 2-C4H3SCOCF3) generated a variety of tin(II) alkoxides (1−4) in high yield. The activated terminal alkynes (HC≡CCO2R, R = Me, Et) react with LSnH to yield the tin(II) substituted terminal alkenes (5−6) instead of dihydrogen elimination although the Sn−H and C−H bonds are differently polarized. Furthermore, LSnH reacts with disubstituted alkyne (RO2CC≡CCO2R, R = Et, tBu) in toluene at room temperature to form the stannylene substituted internal alkenes (7−8). Compounds 1−8 were characterized by microanalysis and multinuclear NMR spectroscopy. Moreover compounds 3, 4, 5, and 7 were characterized by X-ray crystallography, and the resulting structures confirmed the monomeric nature, in which the tin centers reside in a trigonal-pyramidal environment." @default.
• W2032656075 created "2016-06-24" @default.
• W2032656075 creator A5044418069 @default.
• W2032656075 creator A5047561467 @default.
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• W2032656075 date "2009-09-08" @default.
• W2032656075 modified "2023-10-18" @default.
• W2032656075 title "Hydrostannylation of Ketones and Alkynes with LSnH [L = HC(CMeNAr)₂, Ar = 2,6-<i>i</i>Pr₂C₆H₃]" @default.
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• W2032656075 doi "https://doi.org/10.1021/ic9012069" @default.
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