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- W2032677228 abstract "The room temperature EPR spectra of γ-irradiated crystals of DL-threonine, CH3CH(OH)CH(N+H3)CO2−, and of deuterated DL-threonine, CH3CH(OD)CH(N+D3)CO2−, have been studied. Both crystals show complex spectra resulting from the overlap of signals from two different paramagnetic species. In the deuterated crystal, the EPR spectrum was simplified by uv photobleaching to remove one paramagnetic species. The remaining, stable radical has been identified as CH3Ċ(OD)CH(N+D3)CO2−, resulting from an H abstraction. Similarly, the stable radical remaining in the uv photobleached normal crystal was identified as CH3Ċ(OH)CH(N+H3)CO2−. The observed hyperfine couplings are AβH=32.8 G, AmethylH =19.1 G, AβN =4.4 G, and AOHH [[inverted lazy s]] 3 G. Precise determination of g values has not been possible. Using the known crystal structure of DL-threonine and the measured hyperfine coupling constants, we have calculated the orientation of the damaged molecule in the host crystal." @default.
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- W2032677228 date "1974-04-01" @default.
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- W2032677228 title "EPR of γ‐irradiated crystals of DL‐threonine at room temperature" @default.
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- W2032677228 doi "https://doi.org/10.1063/1.1681451" @default.
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