Matches in SemOpenAlex for { <https://semopenalex.org/work/W2032682854> ?p ?o ?g. }
Showing items 1 to 98 of
98
with 100 items per page.
- W2032682854 endingPage "627" @default.
- W2032682854 startingPage "621" @default.
- W2032682854 abstract "A dielectric property study was performed across a wide range of frequencies and temperatures onring opening polymerisation of ε-caprolactone system in order to relate quantitatively their dielectric properties to microwave heating mechanisms. An analysis of the results concluded that heating mechanism of the polymerisation mixtures in a microwave field was controlled by the dielectric properties of monomer, where the monomer was the major component (>90 % volume/volume) as well as the component with highest dielectric loss and dissipation factor. The penetration depth of mixtures at 2.45 GHz was noted to increase from ~0.58 cm (at 20 C) to ~3.3 cm (at 150 °C). This small penetration depth limits the potential to achieve the successful scale up of a microwave-assisted polymerisation of ε-caprolactone in batch mode at 2.45 GHz. As a result, this will lead to inhomogeneous bulk temperature distribution within the polymerisation mixture and irreproducible chemistry. However, a fast heating rate based on a high value of dissipation factor and dielectric loss of the polymerisation mixtures shows potential to enable the reaction to be completed in a few seconds that may allow the polymerisation to be transferred to a continuous flow process. In so doing, small diameter tubular reactors can be employed hence removing this penetration depth issue. Thus, the polymerisation mixtures dielectric properties are worth to be considered to ensure the reliability and reproducibility of the microwave assisted synthesis of poly-ε-caprolactone at large scale production." @default.
- W2032682854 created "2016-06-24" @default.
- W2032682854 creator A5014745497 @default.
- W2032682854 creator A5039279869 @default.
- W2032682854 creator A5050182499 @default.
- W2032682854 creator A5090492014 @default.
- W2032682854 date "2014-01-01" @default.
- W2032682854 modified "2023-09-26" @default.
- W2032682854 title "Dielectric Properties for the Ring Opening Polymerisation of ε-Caprolactone" @default.
- W2032682854 cites W1965311371 @default.
- W2032682854 cites W1984041712 @default.
- W2032682854 cites W1990250229 @default.
- W2032682854 cites W1998375650 @default.
- W2032682854 cites W2005845135 @default.
- W2032682854 cites W2018043097 @default.
- W2032682854 cites W2020974370 @default.
- W2032682854 cites W2026039351 @default.
- W2032682854 cites W2075417766 @default.
- W2032682854 cites W2078049308 @default.
- W2032682854 cites W2094362263 @default.
- W2032682854 cites W2135977363 @default.
- W2032682854 doi "https://doi.org/10.4028/www.scientific.net/amm.493.621" @default.
- W2032682854 hasPublicationYear "2014" @default.
- W2032682854 type Work @default.
- W2032682854 sameAs 2032682854 @default.
- W2032682854 citedByCount "1" @default.
- W2032682854 countsByYear W20326828542014 @default.
- W2032682854 crossrefType "journal-article" @default.
- W2032682854 hasAuthorship W2032682854A5014745497 @default.
- W2032682854 hasAuthorship W2032682854A5039279869 @default.
- W2032682854 hasAuthorship W2032682854A5050182499 @default.
- W2032682854 hasAuthorship W2032682854A5090492014 @default.
- W2032682854 hasConcept C120665830 @default.
- W2032682854 hasConcept C121332964 @default.
- W2032682854 hasConcept C127413603 @default.
- W2032682854 hasConcept C133386390 @default.
- W2032682854 hasConcept C135402231 @default.
- W2032682854 hasConcept C159985019 @default.
- W2032682854 hasConcept C166940927 @default.
- W2032682854 hasConcept C186145619 @default.
- W2032682854 hasConcept C188027245 @default.
- W2032682854 hasConcept C192562407 @default.
- W2032682854 hasConcept C193493375 @default.
- W2032682854 hasConcept C2781111393 @default.
- W2032682854 hasConcept C42360764 @default.
- W2032682854 hasConcept C42475967 @default.
- W2032682854 hasConcept C44228677 @default.
- W2032682854 hasConcept C44838205 @default.
- W2032682854 hasConcept C49040817 @default.
- W2032682854 hasConcept C521977710 @default.
- W2032682854 hasConcept C62520636 @default.
- W2032682854 hasConcept C80107235 @default.
- W2032682854 hasConcept C91066073 @default.
- W2032682854 hasConcept C97274863 @default.
- W2032682854 hasConcept C97355855 @default.
- W2032682854 hasConceptScore W2032682854C120665830 @default.
- W2032682854 hasConceptScore W2032682854C121332964 @default.
- W2032682854 hasConceptScore W2032682854C127413603 @default.
- W2032682854 hasConceptScore W2032682854C133386390 @default.
- W2032682854 hasConceptScore W2032682854C135402231 @default.
- W2032682854 hasConceptScore W2032682854C159985019 @default.
- W2032682854 hasConceptScore W2032682854C166940927 @default.
- W2032682854 hasConceptScore W2032682854C186145619 @default.
- W2032682854 hasConceptScore W2032682854C188027245 @default.
- W2032682854 hasConceptScore W2032682854C192562407 @default.
- W2032682854 hasConceptScore W2032682854C193493375 @default.
- W2032682854 hasConceptScore W2032682854C2781111393 @default.
- W2032682854 hasConceptScore W2032682854C42360764 @default.
- W2032682854 hasConceptScore W2032682854C42475967 @default.
- W2032682854 hasConceptScore W2032682854C44228677 @default.
- W2032682854 hasConceptScore W2032682854C44838205 @default.
- W2032682854 hasConceptScore W2032682854C49040817 @default.
- W2032682854 hasConceptScore W2032682854C521977710 @default.
- W2032682854 hasConceptScore W2032682854C62520636 @default.
- W2032682854 hasConceptScore W2032682854C80107235 @default.
- W2032682854 hasConceptScore W2032682854C91066073 @default.
- W2032682854 hasConceptScore W2032682854C97274863 @default.
- W2032682854 hasConceptScore W2032682854C97355855 @default.
- W2032682854 hasLocation W20326828541 @default.
- W2032682854 hasOpenAccess W2032682854 @default.
- W2032682854 hasPrimaryLocation W20326828541 @default.
- W2032682854 hasRelatedWork W1635461530 @default.
- W2032682854 hasRelatedWork W2032682854 @default.
- W2032682854 hasRelatedWork W2112355878 @default.
- W2032682854 hasRelatedWork W2342349820 @default.
- W2032682854 hasRelatedWork W2589431698 @default.
- W2032682854 hasRelatedWork W3121826571 @default.
- W2032682854 hasRelatedWork W3156907320 @default.
- W2032682854 hasRelatedWork W4223643463 @default.
- W2032682854 hasRelatedWork W4280616684 @default.
- W2032682854 hasRelatedWork W4297749091 @default.
- W2032682854 hasVolume "493" @default.
- W2032682854 isParatext "false" @default.
- W2032682854 isRetracted "false" @default.
- W2032682854 magId "2032682854" @default.
- W2032682854 workType "article" @default.