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- W2032709880 abstract "Four isostructural metal monophosphonates, M{(2-C(5)H(4)NO)CH(2)PO(3)}(H(2)O)(2) with M = Co (1), Ni (2), Mn (3), and Cd (4), were synthesized and structurally characterized. These compounds show a double-chain structure in which the M(2)(μ-O)(2) dimers are connected by O-P-O bridges. The magnetic responses of 1-3 were investigated over a wide range of magnetic fields (up to 10 T) and temperatures (down to 50 mK). Except for 4, which is weakly diamagnetic from 2 K to room temperature, the dominant magnetic interactions are antiferromagnetic. Isothermal magnetic field sweeps at 50 mK provide signatures in the magnetic responses that are associated with antiferromagnetic to field-induced fully polarized (magnetically saturated) transitions. Analysis of the magnetic data indicates that 1 and 2 form magnetic dimer-like clusters with weak dimer-dimer interactions present. Contrastingly, the magnetic interactions present in 3 are significantly weaker, so a definitive description of the magnetism of this compound is elusive." @default.
- W2032709880 created "2016-06-24" @default.
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- W2032709880 date "2010-08-24" @default.
- W2032709880 modified "2023-09-23" @default.
- W2032709880 title "Metal Monophosphonates M{(2-C<sub>5</sub>H<sub>4</sub>NO)CH<sub>2</sub>PO<sub>3</sub>}(H<sub>2</sub>O)<sub>2</sub> (M = Co, Ni, Mn, Cd): Synthesis, Structure, and Magnetism" @default.
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- W2032709880 doi "https://doi.org/10.1021/ic101033n" @default.
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