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- W2032722079 abstract "In this study, a novel material for the electrochemical determination of 17β-estradiol using an electrode based on reduced graphene oxide and a metal complex porphyrin has been applied to environmental monitoring. The electrochemical profile of the proposed electrode was analyzed by differential pulse voltammetry, which showed a shift of the oxidation peak potential of 17β-estradiol to 150mV in a less positive direction compared to the bare reduced graphene oxide electrode. DPV experiments were performed in PBS at pH 7.0 to determine 17β-estradiol without any previous step of extraction, cleanup, or derivatization, in the range of 0.1-1.0μmolL(-1) with a detection limit archived at 5.3nmolL(-1) (1.4μgL(-1)). The proposed sensor was successfully applied in the determination of 17β-estradiol in a river water sample without any purification step and was successfully analyzed under the standard addition method. All the obtained results were in agreement with those from the HPLC procedure." @default.
- W2032722079 created "2016-06-24" @default.
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- W2032722079 date "2015-06-01" @default.
- W2032722079 modified "2023-10-16" @default.
- W2032722079 title "Sensitive determination of 17β-estradiol in river water using a graphene based electrochemical sensor" @default.
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- W2032722079 doi "https://doi.org/10.1016/j.aca.2015.04.043" @default.
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