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- W2032748466 abstract "Significant quantities of silver can be accommodated in galena as a coupled substitution with Ag + Sb and/or Ag + Bi for 2 Pb atoms. The limitations of this solubility are quantified experimentally for the cubic (Fm3̅m) α-galena phase. Above 441.7 °C, the α-galena phase has complete solid solution across the Pb2S2-AgSbS2-AgBiS2 (galena-miargyrite-matildite) ternary. Dry sinter experiments at 400, 375, and 350 °C extend the known miscibility gap on the Pb2S2-AgSbS2 binary into ternary compositions. Phase equilibrium and miscibility gap data and self-consistent thermodynamic data for other high-temperature phases in this system combined with data for other sulfides and sulfosalts are used to constrain an asymmetric regular solution model for the α-galena phase (Pb2,AgSb,AgBi) S2. Phase relations in this system suggest that simple retrograde re-equilibration during cooling can produce phase assemblages and textures commonly observed in Ag-bearing ore deposits. Bulk metal ratios of deposits in conjunction with the application of this thermodynamic model may be used to understand district Ag-distribution or as an exploration tool." @default.
- W2032748466 created "2016-06-24" @default.
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- W2032748466 date "2008-10-01" @default.
- W2032748466 modified "2023-10-18" @default.
- W2032748466 title "A solution model for high-temperature PbS-AgSbS2-AgBiS2 galena" @default.
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- W2032748466 doi "https://doi.org/10.2138/am.2008.2695" @default.
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