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- W2032751054 abstract "Three types of peptide lipids having different numbers of hydroxyl groups in their head moieties, (HO)C5Ala2Cn, QC5Ala2Cn and Q2LysC5Ala2Cn (n=14, 16), were prepared, and their morphological behavior was investigated by various physical techniques: negative staining and freeze-fracture electron microscopy, low-angle X-ray diffraction, selected area electron diffraction, fluorescence polarization spectroscopy, and differential scanning calorimetry. QC5Ala2Cn, having four hydroxyl groups in the head moiety, underwent aggregation in the aqueous dispersion state to afford the nonbilayer phase, which was constituted with highly developed globular domains with face-centered cubic (CII) lattice, above the phase transition temperature (Tm). This CII phase was transformed into the bilayer one below Tm. On the other hand, Q2LysC5Ala2Cn, having eight hydroxyl groups in the head moiety, formed bilayer aggregates in a whole temperature range, above and below Tm. Deprotonation of the hydroxyl groups of QC5Ala2Cn and Q2..." @default.
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- W2032751054 date "1987-04-01" @default.
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- W2032751054 title "Aggregate Morphology of Peptide Lipids Having Hydroxyl Groups: Molecular Basis for Formation of Inverted Hexagonal, Inverted Cubic, Bilayer, and Micellar Phases" @default.
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- W2032751054 doi "https://doi.org/10.1246/bcsj.60.1469" @default.
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