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- W2032776210 abstract "Abstract Benzaldehyde derivatives of cellulose were prepared by reaction of amino derivatives of powder or bead cellulose with 4-isothiocyanato benzaldehyde in a water-dioxane-buffered neural medium. Rapid reactions of benzaldehyde cellulose derivatives with thiols (benzyl [35S] mercaptan, cysteine, reduced glutasthione) produced thioacetal and hemithioacetal cellulose derivatives in strongly acid (pH ≈ 0.5) and less acid or neuralmedia, respectively. Selective reaction with thiols, even in presence of other nucleophiles (benzylamine benzyl alcohol), was ensured in strongly acid medium while the presence of amine in neutral medium caused an increase of thiol sorption up 300%. The kinetics of formation of thioacetal cellulose derivatives were found to be a good model for sorption kinetics, allowing their transformation to linear form. This procedure allows a rapid estimation of carrier sorption capacity and sorption half-time." @default.
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- W2032776210 date "1984-03-01" @default.
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- W2032776210 title "Selective chemisorbents. Part 3: Selective binding of thiols to benzaldehyde derivatives of cellulose" @default.
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- W2032776210 doi "https://doi.org/10.1016/0167-6989(84)90134-x" @default.
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