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- W2032788698 abstract "Abstract The one-pot reaction of 1-tetralone with nitriles in the presence of triflic anhydride affords in good yields 2,4-disubstituted 5,6-dihydrobenzo[ h ]quinazolines, which oxidation with DDQ leads to the corresponding benzo[ h ]quinazolines. 2-Tetralone undergoes identical process forming 1,3-disubstituted 5,6-dihydrobenzo[ f ]quinazolines. However, when the reaction of 2-tetralone is carried out with methylthiocyanate as nitrile, 5-methylthiotetrahydrodibenzo[ a , i ]phenanthridines are isolated in good yields. Easy transformations of the methylthio group offer possible access to a variety of substituted dibenzo[ a , i ]phenanthridines." @default.
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- W2032788698 date "2006-06-27" @default.
- W2032788698 modified "2023-10-18" @default.
- W2032788698 title "The Reaction of Tetralones with Nitriles: A Simple Approach to the Synthesis of New Substituted Benzo[h]quinazolines, Benzo[f]quinazolines and Dibenzo[a,i]phenanthridines." @default.
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- W2032788698 doi "https://doi.org/10.1002/chin.200626140" @default.
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