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- W2032802718 abstract "The influence of convection on the degree of redox cycling at interdigitated microarray electrodes in a flow system was investigated in the end column detection mode for flow rates below 20 µL/min. It was found that the degree of redox cycling increased with decreasing flow rates and values of 2.9 and 2.2 were obtained for a flow rate of 2 and 20 µL/min, respectively, using photolithographically fabricated interdigitated arrays consisting of 140 microbands separated by 6 µm. The obtained degrees of redox cycling were lower than the value of 4.4 obtained in a stationary solution in the batch mode as a result of a decreased collection efficiency between adjacent microbands and a relatively low conversion efficiency at each microband in the presence of the flow. It is shown that a collection efficiency of more than 90 % is needed to produce an order of magnitude increase in the current due to redox cycling in a stationary solution. When using a microarray electrode consisting of 280 microbands in a thin layer flow cell, a conversion efficiency of close to 100 % could be obtained at flow rates below 1 µL/min. In the latter case, a significantly larger flow rate dependence of the current was found compared to that for a single microband electrode." @default.
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- W2032802718 date "2000-03-01" @default.
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- W2032802718 title "Electrochemical Detection Based on Redox Cycling Using Interdigitated Microarray Electrodes at µL/min Flow Rates" @default.
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- W2032802718 doi "https://doi.org/10.1002/(sici)1521-4109(20000301)12:4<255::aid-elan255>3.0.co;2-7" @default.
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