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- W2032804975 abstract "Abstract Es wird eine neue effiziente Synthese für Tetracyanoborate im molaren Maßstab ausgehend von den leicht zugänglichen Reagenzien K[BF 4 ], LiCl und KCN beschrieben. Das nach dem Sinter‐Prozess und Aufarbeitung erhaltene Tetracyanoborat ist im Gegensatz zu den Produkten der bisher bekannten Reaktionen ein weißer Feststoff, der frei von Verunreinigungen ist. Das thermische Verhalten der gemischten Cyanofluoroborate, K[BF x (CN) 4— x ] ( x = 1—3), wurde näher untersucht, um den Mechanismus des Ligandenaustausches bei der K[B(CN) 4 ]‐Synthese aufzuklären. Weiterhin werden einige Metathese‐Reaktionen für die Herstellung unterschiedlicher Tetracyanoborate beschrieben." @default.
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- W2032804975 date "2003-07-01" @default.
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- W2032804975 title "Eine effiziente Synthese von Tetracyanoboraten durch Sinterprozesse" @default.
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- W2032804975 doi "https://doi.org/10.1002/zaac.200300047" @default.
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