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• W2032806962 abstract "We present HPLC/UV/MS evidence to support the identification of benzo[ghi]naphtho[8,1,2-bcd]perylene as a product of supercritical toluene pyrolysis. Mass spectral data confirm that compound I-eluting in between co-eluting benzo[a]coronene/phenanthro[5,4,3,2-efghi]perylene and benzo[pqr]naphtho[8,1,2-bcd]perylene, all three of which have been unequivocally identified as C(28)H(14) products of toluene pyrolysis-is also a C(28)H(14) product component. The UV spectrum of compound I is presented, and indicates that it is a benzenoid polycyclic aromatic hydrocarbon (PAH). Five of the eight benzenoid C(28)H(14) PAH isomers have published UV spectra, and characteristics of the remaining three are deduced from annelation theory. Only one of these compounds, benzo[ghi]naphtho[8,1,2-bcd]perylene, is predicted to have a UV spectrum with characteristics that we find in the spectrum of compound I. In addition, benzo[ghi]naphtho[8,1,2-bcd]perylene is the only benzenoid C(28)H(14) isomer whose length-to-breadth ratio is consistent with the HPLC retention time of compound I. The reaction mechanism through which benzo[ghi]naphtho[8,1,2-bcd]perylene is formed in this environment is shown, and is consistent with reaction pathways of other large PAH found in this product mixture." @default.
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• W2032806962 date "2006-09-01" @default.
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• W2032806962 title "First identification of benzo[ghi]naphtho[8,1,2-bcd]perylene as a product of fuel pyrolysis, using high-performance liquid chromatography with diode-array ultraviolet-visible absorbance detection and mass spectrometry" @default.
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• W2032806962 doi "https://doi.org/10.1016/j.chroma.2006.05.101" @default.
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