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- W2032810239 startingPage "1644" @default.
- W2032810239 abstract "The kinetic measurements of the Hofmann rearrangement of 2,4-, 2,5- 2,6-, and 3,5-disubstituted N-chlorobenzamides were carried out. The rate constants of 4- and 5-substituted 2-chloro-N-chlorobenzamides were applicable to the LArSR relationship: logk⁄k0=−2.21(σ0+0.69ΔbarσR+)+0.003 indicating that the reactivity of the 2-chloro series was subjected to a larger additional conjugation effect than that of the 2-unsubstituted series. The detailed discussion of the reaction mechanism on the basis of these results supported strongly the concerted mechanism." @default.
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- W2032810239 date "1971-06-01" @default.
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- W2032810239 title "The Hofmann Rearrangement. III. Kinetic Substituent Effects of 4- and 5-Substituted 2-Chloro-<i>N</i>-chlorobenzamides" @default.
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