Matches in SemOpenAlex for { <https://semopenalex.org/work/W2032839084> ?p ?o ?g. }
- W2032839084 endingPage "1464" @default.
- W2032839084 startingPage "1457" @default.
- W2032839084 abstract "Perfluorosulfonic acid (PFSA) ionomer membranes are ion-conducting polymers with high water sorption capacity and thermo-mechanical stability. The morphology of PFSA changes during sorption affecting the mechanical and physical properties of the membrane. In this work, we investigate the structure-property relationship in swollen PFSA membranes using three proposed nanostructural descriptions and determine Young's modulus of the membrane at a wide range of temperatures (−20–85 °C) and water volume fractions (0–0.5) for these configurations. Comparing the mechanics-based models with experimental data we propose that ion-rich water domains in PFSA membrane are spherical at low water content, spherical with connecting channels at intermediate water content and cylindrical at high water contents. Furthermore, our findings indicate that the scaling behavior for Young's modulus of PFSA ionomers is similar to that of aerogels. This suggests, from a mechanics perspective, that aerogels and ionomers may have a similar interconnected porous nanostructure where some solid regions do not contribute to the mechanical load-bearing capacity." @default.
- W2032839084 created "2016-06-24" @default.
- W2032839084 creator A5032036023 @default.
- W2032839084 creator A5035827776 @default.
- W2032839084 creator A5075633518 @default.
- W2032839084 date "2010-03-01" @default.
- W2032839084 modified "2023-10-11" @default.
- W2032839084 title "Structure-property relationship in ionomer membranes" @default.
- W2032839084 cites W1903915324 @default.
- W2032839084 cites W1969498402 @default.
- W2032839084 cites W1972585338 @default.
- W2032839084 cites W1975367353 @default.
- W2032839084 cites W1981122307 @default.
- W2032839084 cites W1983021483 @default.
- W2032839084 cites W1984717573 @default.
- W2032839084 cites W1988320685 @default.
- W2032839084 cites W1988422679 @default.
- W2032839084 cites W1989450404 @default.
- W2032839084 cites W1997900740 @default.
- W2032839084 cites W1997947518 @default.
- W2032839084 cites W2000616320 @default.
- W2032839084 cites W2001898276 @default.
- W2032839084 cites W2003453488 @default.
- W2032839084 cites W2003488635 @default.
- W2032839084 cites W2006398273 @default.
- W2032839084 cites W2006579745 @default.
- W2032839084 cites W2007294972 @default.
- W2032839084 cites W2007511818 @default.
- W2032839084 cites W2015176992 @default.
- W2032839084 cites W2015928039 @default.
- W2032839084 cites W2018089352 @default.
- W2032839084 cites W2019617738 @default.
- W2032839084 cites W2024695734 @default.
- W2032839084 cites W2028422519 @default.
- W2032839084 cites W2028755780 @default.
- W2032839084 cites W2033234421 @default.
- W2032839084 cites W2037523420 @default.
- W2032839084 cites W2039107936 @default.
- W2032839084 cites W2043068789 @default.
- W2032839084 cites W2044307855 @default.
- W2032839084 cites W2046614246 @default.
- W2032839084 cites W2046639856 @default.
- W2032839084 cites W2051360173 @default.
- W2032839084 cites W2051599603 @default.
- W2032839084 cites W2051939800 @default.
- W2032839084 cites W2055470966 @default.
- W2032839084 cites W2055714184 @default.
- W2032839084 cites W2060577895 @default.
- W2032839084 cites W2061341731 @default.
- W2032839084 cites W2063239405 @default.
- W2032839084 cites W2064428962 @default.
- W2032839084 cites W2065033779 @default.
- W2032839084 cites W2065799704 @default.
- W2032839084 cites W2068678131 @default.
- W2032839084 cites W2075526320 @default.
- W2032839084 cites W2076058822 @default.
- W2032839084 cites W2078154064 @default.
- W2032839084 cites W2078453988 @default.
- W2032839084 cites W2079775184 @default.
- W2032839084 cites W2079930781 @default.
- W2032839084 cites W2085519119 @default.
- W2032839084 cites W2085872790 @default.
- W2032839084 cites W2087594700 @default.
- W2032839084 cites W2091252781 @default.
- W2032839084 cites W2094255943 @default.
- W2032839084 cites W2103993262 @default.
- W2032839084 cites W2108847594 @default.
- W2032839084 cites W2112944855 @default.
- W2032839084 cites W2117861466 @default.
- W2032839084 cites W2124360809 @default.
- W2032839084 cites W2124787352 @default.
- W2032839084 cites W2136968473 @default.
- W2032839084 cites W2141607915 @default.
- W2032839084 cites W2142065917 @default.
- W2032839084 cites W2142602576 @default.
- W2032839084 cites W2144740627 @default.
- W2032839084 cites W2145556107 @default.
- W2032839084 cites W2156340471 @default.
- W2032839084 cites W2156564617 @default.
- W2032839084 cites W2159038917 @default.
- W2032839084 cites W2165346850 @default.
- W2032839084 cites W2167284208 @default.
- W2032839084 cites W2169280098 @default.
- W2032839084 cites W2171950277 @default.
- W2032839084 cites W2498633197 @default.
- W2032839084 cites W2991957114 @default.
- W2032839084 cites W92192243 @default.
- W2032839084 doi "https://doi.org/10.1016/j.polymer.2010.01.046" @default.
- W2032839084 hasPublicationYear "2010" @default.
- W2032839084 type Work @default.
- W2032839084 sameAs 2032839084 @default.
- W2032839084 citedByCount "27" @default.
- W2032839084 countsByYear W20328390842012 @default.
- W2032839084 countsByYear W20328390842013 @default.
- W2032839084 countsByYear W20328390842014 @default.
- W2032839084 countsByYear W20328390842015 @default.
- W2032839084 countsByYear W20328390842016 @default.
- W2032839084 countsByYear W20328390842017 @default.