Matches in SemOpenAlex for { <https://semopenalex.org/work/W2032839216> ?p ?o ?g. }
Showing items 1 to 84 of
84
with 100 items per page.
- W2032839216 endingPage "619" @default.
- W2032839216 startingPage "616" @default.
- W2032839216 abstract "Stopped-flow experiments are usually performed with optical detection. In case of low absorptivities or low concentrations of the measured substances a very high sensitivity is necessary. A special optical detection system with this feature is described. By a differential configuration of the detectors and the use of high light intensities fluctuations of the light source and detector shot noise were greatly reduced in their effects. The detection system is capable of performing extremely sensitive kinetic measurements from 290 to 620 nm within the time-scale of stopped-flow experiments. Kinetic traces with a full scale absorbance down to 5 · 10−4 were recorded. In this extreme case, the signal to noise ratio was still as good as 25:1. With typical values for absorptivities, optical path length, and dead time, even diffusion controlled electron transfer reactions could thus be observed in a stopped-flow apparatus." @default.
- W2032839216 created "2016-06-24" @default.
- W2032839216 creator A5077114498 @default.
- W2032839216 date "1987-06-01" @default.
- W2032839216 modified "2023-09-26" @default.
- W2032839216 title "Extremely Sensitive Optical Detection System for Stopped-flow Measurements of Reactions with Very High Rate Constants or Small Absorbance Changes" @default.
- W2032839216 cites W1929218589 @default.
- W2032839216 cites W1990732022 @default.
- W2032839216 cites W2023858428 @default.
- W2032839216 cites W2028973919 @default.
- W2032839216 cites W2065699167 @default.
- W2032839216 cites W2083769915 @default.
- W2032839216 cites W2144970998 @default.
- W2032839216 cites W2318075081 @default.
- W2032839216 doi "https://doi.org/10.1002/bbpc.19870910608" @default.
- W2032839216 hasPublicationYear "1987" @default.
- W2032839216 type Work @default.
- W2032839216 sameAs 2032839216 @default.
- W2032839216 citedByCount "1" @default.
- W2032839216 crossrefType "journal-article" @default.
- W2032839216 hasAuthorship W2032839216A5077114498 @default.
- W2032839216 hasConcept C113196181 @default.
- W2032839216 hasConcept C115961682 @default.
- W2032839216 hasConcept C120665830 @default.
- W2032839216 hasConcept C121332964 @default.
- W2032839216 hasConcept C127413603 @default.
- W2032839216 hasConcept C135889238 @default.
- W2032839216 hasConcept C154945302 @default.
- W2032839216 hasConcept C185592680 @default.
- W2032839216 hasConcept C199360897 @default.
- W2032839216 hasConcept C21200559 @default.
- W2032839216 hasConcept C24326235 @default.
- W2032839216 hasConcept C2779843651 @default.
- W2032839216 hasConcept C41008148 @default.
- W2032839216 hasConcept C43617362 @default.
- W2032839216 hasConcept C62520636 @default.
- W2032839216 hasConcept C69357855 @default.
- W2032839216 hasConcept C72659945 @default.
- W2032839216 hasConcept C94915269 @default.
- W2032839216 hasConcept C97355855 @default.
- W2032839216 hasConcept C98015330 @default.
- W2032839216 hasConcept C99498987 @default.
- W2032839216 hasConceptScore W2032839216C113196181 @default.
- W2032839216 hasConceptScore W2032839216C115961682 @default.
- W2032839216 hasConceptScore W2032839216C120665830 @default.
- W2032839216 hasConceptScore W2032839216C121332964 @default.
- W2032839216 hasConceptScore W2032839216C127413603 @default.
- W2032839216 hasConceptScore W2032839216C135889238 @default.
- W2032839216 hasConceptScore W2032839216C154945302 @default.
- W2032839216 hasConceptScore W2032839216C185592680 @default.
- W2032839216 hasConceptScore W2032839216C199360897 @default.
- W2032839216 hasConceptScore W2032839216C21200559 @default.
- W2032839216 hasConceptScore W2032839216C24326235 @default.
- W2032839216 hasConceptScore W2032839216C2779843651 @default.
- W2032839216 hasConceptScore W2032839216C41008148 @default.
- W2032839216 hasConceptScore W2032839216C43617362 @default.
- W2032839216 hasConceptScore W2032839216C62520636 @default.
- W2032839216 hasConceptScore W2032839216C69357855 @default.
- W2032839216 hasConceptScore W2032839216C72659945 @default.
- W2032839216 hasConceptScore W2032839216C94915269 @default.
- W2032839216 hasConceptScore W2032839216C97355855 @default.
- W2032839216 hasConceptScore W2032839216C98015330 @default.
- W2032839216 hasConceptScore W2032839216C99498987 @default.
- W2032839216 hasIssue "6" @default.
- W2032839216 hasLocation W20328392161 @default.
- W2032839216 hasOpenAccess W2032839216 @default.
- W2032839216 hasPrimaryLocation W20328392161 @default.
- W2032839216 hasRelatedWork W1977992002 @default.
- W2032839216 hasRelatedWork W2018310814 @default.
- W2032839216 hasRelatedWork W2026078926 @default.
- W2032839216 hasRelatedWork W2033189009 @default.
- W2032839216 hasRelatedWork W2035984224 @default.
- W2032839216 hasRelatedWork W2061995460 @default.
- W2032839216 hasRelatedWork W2085535279 @default.
- W2032839216 hasRelatedWork W2103695441 @default.
- W2032839216 hasRelatedWork W2379998056 @default.
- W2032839216 hasRelatedWork W4292387587 @default.
- W2032839216 hasVolume "91" @default.
- W2032839216 isParatext "false" @default.
- W2032839216 isRetracted "false" @default.
- W2032839216 magId "2032839216" @default.
- W2032839216 workType "article" @default.