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- W2032847557 abstract "The primary step in the electrocrystallization of Na[PcCo(CN)2], i.e. adsorption of an electrooxidation intermediate of this complex, is investigated by cyclic voltammetry. Experimental i/E curves are compared to those generated by digital simulation. The simulated mechanistic model involves an reaction sequence (where C corresponds to the cleavage of a CN− ligand) and coadsorption of both coordinatively unsaturated partners of the second electron transfer. The adsorption parameters, the relative values of the redox potentials of the two electron transfers, and the rate constant for the CN− cleavage step were varied in the simulations. Estimations for their values in the case of Na[PcCo(CN)2] are derived." @default.
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- W2032847557 date "1991-06-01" @default.
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- W2032847557 title "The mechanism of Na[PcCo(CN2)] electrocrystallization - analysis of adsorption phenomena by a comparison of simulated and experimental cyclic voltammograms" @default.
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- W2032847557 doi "https://doi.org/10.1016/0379-6779(91)91220-5" @default.
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