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- W2032851955 abstract "A study of vinyl chloride on Ag(1 1 1) by thermal desorption spectroscopy (TDS) and high resolution electron energy loss spectroscopy indicates that vinyl chloride is weakly adsorbed with the molecular plane approximately parallel to the Ag(1 1 1) surface plane. The monolayer desorbs molecularly at 119 K in a first order process with desorption activation energy of 6.7 kcal/mol and prefactor of 4.6×1011 s−1. The first few multilayers above the monolayer desorb molecularly at 92 K with an activation energy of 4.3 kcal/mol. At low vinyl chloride coverages TDS has the resolution to allow the observation that as the Ag(1 1 1) surface is heated to greater than 126 K, a small portion (<20%) of the adsorbed vinyl chloride dissociates with an estimated activation energy of 8 kcal/mol, into vinyl and Cl, which adsorb on Ag(1 1 1). Further heating to temperatures greater than 155 K results in vinyl and Cl recombination with subsequent molecular desorption in a second order process with desorption activation energy of 10.7 kcal/mol and prefactor of 2.3×10−3 cm2/molecule s." @default.
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- W2032851955 date "2003-01-01" @default.
- W2032851955 modified "2023-10-17" @default.
- W2032851955 title "Adsorption structure, energetics, and thermal reactions of vinyl chloride on Ag()" @default.
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- W2032851955 doi "https://doi.org/10.1016/s0039-6028(02)02333-6" @default.
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