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- W2032860922 abstract "Abstract Summary: Chemical shift trends in the methylene and α substituent regions of 13 C NMR spectra of vinyl polymers have been analyzed in terms of a three‐state rotational isomeric states (RIS) model and the γ ‐ gauche effect. In this framework, it has been demonstrated that the three sequencing rules observed for poly(propylene) can also be expected to work for many other vinyl polymers. The first two rules, justified in terms of the conformational perturbability of stereosequences, turn out to be respected by a considerable number of NMR spectra. On the other hand, the same spectral data are in substantial disagreement with the third rule. An explanation is proposed for this breakdown. Sketches of the three conformations expected for rotation on the two prochiral bonds flanking the methine carbon of a vinyl polymer. magnified image Sketches of the three conformations expected for rotation on the two prochiral bonds flanking the methine carbon of a vinyl polymer." @default.
- W2032860922 created "2016-06-24" @default.
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- W2032860922 date "2004-06-21" @default.
- W2032860922 modified "2023-10-10" @default.
- W2032860922 title "Simple Trends in the Methylene andα-Substituent Regions of NMR Spectra of Vinyl Polymers" @default.
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- W2032860922 doi "https://doi.org/10.1002/macp.200400073" @default.
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