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- W2032886853 abstract "Applying the modified elution gas chromatography method for determination of adsorption isotherms, the adsorption isotherms of n-octane and n-propanol on a bare graphite surface as well as on that precovered with n-hexadecane were determined. From these isotherms the extrapolated film pressure πmax values were calculated from the integrated Gibbs′ adsorption equation, integrating up to saturated vapour pressure. Equating the πmax values of n-octane to the work of wetting, the dispersion free surface energy of graphite was calculated, as a function of surface coverage with n-hexadecane. The obtained values were then discussed in relation to possible structures of hydrocarbon layers. The spreading films of n-octane seemed the most probable in the investigated systems. The dispersion free surface energy of bare graphite was estimated to be 119.5 mJ/m2, which was comparable to the values reported in the literature. The deposited n-hexadecane layers seemed to reduce the surface energy of graphite to 68–70 mJ/m2. Polar interactions of the bare graphite surface were also found." @default.
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- W2032886853 date "1987-11-01" @default.
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- W2032886853 title "Free surface energy changes in graphite/n-hexadecane system" @default.
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- W2032886853 doi "https://doi.org/10.1016/0254-0584(87)90137-4" @default.
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