Matches in SemOpenAlex for { <https://semopenalex.org/work/W2032901436> ?p ?o ?g. }
Showing items 1 to 90 of
90
with 100 items per page.
- W2032901436 endingPage "939" @default.
- W2032901436 startingPage "933" @default.
- W2032901436 abstract "The protonation equilibria of cysteine and its complex formation with the Tl(I) ion were studied over a wide range of pH (1 to 11), using a combination of spectrophotometric and potentiometric methods at constant temperature, 25 °C, different methanol−water mixtures, (0 to 40) % (v/v), and constant ionic strength (0.1 mol·dm−3 sodium perchlorate). Least-squares regression calculations are consistent with the formation of TlH2L+, TlHL, and TlL− species, where L2− represents the fully dissociated ligand. The protonation of cysteine and the formation constants of the formed complexes in different media were analyzed in terms of Kamlet, Abboud, and Taft (KAT) parameters. Single-parameter correlations of the formation constants versus α (hydrogen-bond donor acidity), β (hydrogen-bond acceptor basicity), and for π* (dipolarity/polarizability) are relatively poor in all solutions, but multiparameter correlations represent significant improvements with regard to the single-parameter model. Linear correlation is o..." @default.
- W2032901436 created "2016-06-24" @default.
- W2032901436 creator A5021023621 @default.
- W2032901436 creator A5056254036 @default.
- W2032901436 date "2009-01-22" @default.
- W2032901436 modified "2023-09-26" @default.
- W2032901436 title "Solvent Effects on Protonation and Complexation of Cysteine and Thallium(I) in Different Aqueous Solutions of Methanol" @default.
- W2032901436 cites W1971855049 @default.
- W2032901436 cites W1979126161 @default.
- W2032901436 cites W1982058240 @default.
- W2032901436 cites W1989366444 @default.
- W2032901436 cites W1990152409 @default.
- W2032901436 cites W1992715878 @default.
- W2032901436 cites W2002495913 @default.
- W2032901436 cites W2007058212 @default.
- W2032901436 cites W2018006305 @default.
- W2032901436 cites W2024963472 @default.
- W2032901436 cites W2026163738 @default.
- W2032901436 cites W2027412989 @default.
- W2032901436 cites W2030459058 @default.
- W2032901436 cites W2036310432 @default.
- W2032901436 cites W2050187668 @default.
- W2032901436 cites W2055403369 @default.
- W2032901436 cites W2057003691 @default.
- W2032901436 cites W2062280426 @default.
- W2032901436 cites W2090391132 @default.
- W2032901436 cites W2105686863 @default.
- W2032901436 cites W2111954662 @default.
- W2032901436 cites W2116716969 @default.
- W2032901436 doi "https://doi.org/10.1021/je800712x" @default.
- W2032901436 hasPublicationYear "2009" @default.
- W2032901436 type Work @default.
- W2032901436 sameAs 2032901436 @default.
- W2032901436 citedByCount "6" @default.
- W2032901436 countsByYear W20329014362015 @default.
- W2032901436 countsByYear W20329014362020 @default.
- W2032901436 crossrefType "journal-article" @default.
- W2032901436 hasAuthorship W2032901436A5021023621 @default.
- W2032901436 hasAuthorship W2032901436A5056254036 @default.
- W2032901436 hasConcept C127413603 @default.
- W2032901436 hasConcept C132439834 @default.
- W2032901436 hasConcept C145148216 @default.
- W2032901436 hasConcept C178790620 @default.
- W2032901436 hasConcept C179104552 @default.
- W2032901436 hasConcept C181199279 @default.
- W2032901436 hasConcept C184651966 @default.
- W2032901436 hasConcept C185592680 @default.
- W2032901436 hasConcept C2779201268 @default.
- W2032901436 hasConcept C2779607525 @default.
- W2032901436 hasConcept C2780471494 @default.
- W2032901436 hasConcept C30095370 @default.
- W2032901436 hasConcept C3020166856 @default.
- W2032901436 hasConcept C42360764 @default.
- W2032901436 hasConcept C559099789 @default.
- W2032901436 hasConceptScore W2032901436C127413603 @default.
- W2032901436 hasConceptScore W2032901436C132439834 @default.
- W2032901436 hasConceptScore W2032901436C145148216 @default.
- W2032901436 hasConceptScore W2032901436C178790620 @default.
- W2032901436 hasConceptScore W2032901436C179104552 @default.
- W2032901436 hasConceptScore W2032901436C181199279 @default.
- W2032901436 hasConceptScore W2032901436C184651966 @default.
- W2032901436 hasConceptScore W2032901436C185592680 @default.
- W2032901436 hasConceptScore W2032901436C2779201268 @default.
- W2032901436 hasConceptScore W2032901436C2779607525 @default.
- W2032901436 hasConceptScore W2032901436C2780471494 @default.
- W2032901436 hasConceptScore W2032901436C30095370 @default.
- W2032901436 hasConceptScore W2032901436C3020166856 @default.
- W2032901436 hasConceptScore W2032901436C42360764 @default.
- W2032901436 hasConceptScore W2032901436C559099789 @default.
- W2032901436 hasIssue "3" @default.
- W2032901436 hasLocation W20329014361 @default.
- W2032901436 hasOpenAccess W2032901436 @default.
- W2032901436 hasPrimaryLocation W20329014361 @default.
- W2032901436 hasRelatedWork W1535985604 @default.
- W2032901436 hasRelatedWork W1976604091 @default.
- W2032901436 hasRelatedWork W1989512867 @default.
- W2032901436 hasRelatedWork W2011336653 @default.
- W2032901436 hasRelatedWork W2032901436 @default.
- W2032901436 hasRelatedWork W2055523939 @default.
- W2032901436 hasRelatedWork W2073264102 @default.
- W2032901436 hasRelatedWork W2146877840 @default.
- W2032901436 hasRelatedWork W2951132299 @default.
- W2032901436 hasRelatedWork W3016622961 @default.
- W2032901436 hasVolume "54" @default.
- W2032901436 isParatext "false" @default.
- W2032901436 isRetracted "false" @default.
- W2032901436 magId "2032901436" @default.
- W2032901436 workType "article" @default.