Matches in SemOpenAlex for { <https://semopenalex.org/work/W2032902160> ?p ?o ?g. }
Showing items 1 to 98 of
98
with 100 items per page.
- W2032902160 endingPage "322" @default.
- W2032902160 startingPage "315" @default.
- W2032902160 abstract "Front dynamics in the frontal polymerization of two multifunctional acrylate monomers, 1,6-hexanediol diacrylate (HDDA) and trimethylolpropane ethoxylate triacrylate (TMPTA), with Lupersol 231 [1,1-di(t-butylperoxy)-3,3,5-trimethylcyclohexane] as the initiator, are studied. In most frontal polymerization systems, the dynamics are associated with a planar front propagating through the sample. However, in some cases, front behavior can be altered: the front becomes nonplanar characterized by complex patterns like spin modes and pulsations. To determine how these periodic and aperiodic modes arise, reactant solutions consisting of HDDA diluted with diethyl phthalate (DEP) and TMPTA diluted with dimethyl sulfoxide (DMSO) were used in the study. In the study we reveal frontal behavior characteristic of period-doubling behavior, a doubling of spin heads that degenerate into an apparently chaotic mode. Also, a pulsating symmetric mode has been observed. These observations have a striking similarity to observations made in studies of self-propagating high-temperature synthesis (SHS) in which the addition of an inert diluent afforded a rich variety of dynamical behavior. The degree of cross-linking has also been found to be a bifurcation parameter. The energy of activation of multifunctional acrylate polymerization is a strong function of the degree of polymerization. By adding a monoacrylate (benzyl acrylate: BzAc), such that the front temperature was invariant, we observed a period-doubling bifurcation sequence through changes in the energy of activation, which has not been previously reported. (c) 1999 American Institute of Physics." @default.
- W2032902160 created "2016-06-24" @default.
- W2032902160 creator A5003824597 @default.
- W2032902160 creator A5005601251 @default.
- W2032902160 creator A5011186779 @default.
- W2032902160 creator A5029055177 @default.
- W2032902160 date "1999-06-01" @default.
- W2032902160 modified "2023-09-27" @default.
- W2032902160 title "Period-doubling behavior in frontal polymerization of multifunctional acrylates" @default.
- W2032902160 cites W1977289085 @default.
- W2032902160 cites W1977630217 @default.
- W2032902160 cites W1980415273 @default.
- W2032902160 cites W1982245605 @default.
- W2032902160 cites W1998532451 @default.
- W2032902160 cites W2001905575 @default.
- W2032902160 cites W2010046566 @default.
- W2032902160 cites W2015555580 @default.
- W2032902160 cites W2023934604 @default.
- W2032902160 cites W2031784772 @default.
- W2032902160 cites W2041584581 @default.
- W2032902160 cites W2045628026 @default.
- W2032902160 cites W2047846484 @default.
- W2032902160 cites W2051022934 @default.
- W2032902160 cites W2053513906 @default.
- W2032902160 cites W2062927603 @default.
- W2032902160 cites W2076135125 @default.
- W2032902160 cites W2076611637 @default.
- W2032902160 cites W2077785527 @default.
- W2032902160 cites W2092240939 @default.
- W2032902160 cites W2094092240 @default.
- W2032902160 cites W2100507011 @default.
- W2032902160 cites W2101447125 @default.
- W2032902160 cites W2138949808 @default.
- W2032902160 cites W2153714130 @default.
- W2032902160 cites W2154828578 @default.
- W2032902160 cites W2285408526 @default.
- W2032902160 cites W2342753837 @default.
- W2032902160 doi "https://doi.org/10.1063/1.166408" @default.
- W2032902160 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/12779829" @default.
- W2032902160 hasPublicationYear "1999" @default.
- W2032902160 type Work @default.
- W2032902160 sameAs 2032902160 @default.
- W2032902160 citedByCount "46" @default.
- W2032902160 countsByYear W20329021602012 @default.
- W2032902160 countsByYear W20329021602014 @default.
- W2032902160 countsByYear W20329021602019 @default.
- W2032902160 countsByYear W20329021602020 @default.
- W2032902160 countsByYear W20329021602021 @default.
- W2032902160 countsByYear W20329021602022 @default.
- W2032902160 countsByYear W20329021602023 @default.
- W2032902160 crossrefType "journal-article" @default.
- W2032902160 hasAuthorship W2032902160A5003824597 @default.
- W2032902160 hasAuthorship W2032902160A5005601251 @default.
- W2032902160 hasAuthorship W2032902160A5011186779 @default.
- W2032902160 hasAuthorship W2032902160A5029055177 @default.
- W2032902160 hasBestOaLocation W20329021602 @default.
- W2032902160 hasConcept C121332964 @default.
- W2032902160 hasConcept C153914509 @default.
- W2032902160 hasConcept C159985019 @default.
- W2032902160 hasConcept C174499055 @default.
- W2032902160 hasConcept C188027245 @default.
- W2032902160 hasConcept C192562407 @default.
- W2032902160 hasConcept C44228677 @default.
- W2032902160 hasConcept C521977710 @default.
- W2032902160 hasConcept C97355855 @default.
- W2032902160 hasConceptScore W2032902160C121332964 @default.
- W2032902160 hasConceptScore W2032902160C153914509 @default.
- W2032902160 hasConceptScore W2032902160C159985019 @default.
- W2032902160 hasConceptScore W2032902160C174499055 @default.
- W2032902160 hasConceptScore W2032902160C188027245 @default.
- W2032902160 hasConceptScore W2032902160C192562407 @default.
- W2032902160 hasConceptScore W2032902160C44228677 @default.
- W2032902160 hasConceptScore W2032902160C521977710 @default.
- W2032902160 hasConceptScore W2032902160C97355855 @default.
- W2032902160 hasIssue "2" @default.
- W2032902160 hasLocation W20329021601 @default.
- W2032902160 hasLocation W20329021602 @default.
- W2032902160 hasLocation W20329021603 @default.
- W2032902160 hasLocation W20329021604 @default.
- W2032902160 hasOpenAccess W2032902160 @default.
- W2032902160 hasPrimaryLocation W20329021601 @default.
- W2032902160 hasRelatedWork W1607993531 @default.
- W2032902160 hasRelatedWork W1975646190 @default.
- W2032902160 hasRelatedWork W2008681397 @default.
- W2032902160 hasRelatedWork W2029699554 @default.
- W2032902160 hasRelatedWork W2040165481 @default.
- W2032902160 hasRelatedWork W2602510503 @default.
- W2032902160 hasRelatedWork W2625422444 @default.
- W2032902160 hasRelatedWork W2805492986 @default.
- W2032902160 hasRelatedWork W2884669862 @default.
- W2032902160 hasRelatedWork W4293237221 @default.
- W2032902160 hasVolume "9" @default.
- W2032902160 isParatext "false" @default.
- W2032902160 isRetracted "false" @default.
- W2032902160 magId "2032902160" @default.
- W2032902160 workType "article" @default.