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- W2032912168 abstract "Conformational isomers due to the restricted rotation of the formyl group have been detected in some pyridinecarbaldehydes and non-equivalence has been observed in the symmetric pyridine-4-carbaldehyde, by means of 1H and 13C n.m.r. spectroscopy at low temperature. Assignment of the preferred conformers in pyridine-3-carbaldehyde has been achieved mainly by means of lanthanide shift effects. It has been shown that the carbonyl group shifts the 13C resonance of the syn-ortho-carbon upfield. This can be used as a general method for identifying rotational isomers in analogous derivatives. Barriers to internal rotation have been measured for all the derivatives examined by total line shape analysis of 1H or 13C spectral patterns. In one case both measurements were carried out and substantial agreement was obtained." @default.
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- W2032912168 date "1976-01-01" @default.
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- W2032912168 title "Conformational studies by dynamic nuclear magnetic resonance. Part 4. Rotational isomers and torsional barriers of pyridinecarbaldehydes" @default.
- W2032912168 doi "https://doi.org/10.1039/p29760001791" @default.
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