FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2032920135> ?p ?o ?g. }

• W2032920135 endingPage "139" @default.
• W2032920135 startingPage "133" @default.
• W2032920135 abstract "A thin film of carbon nanofibers embedded into a hydrophobic sol–gel material and deposited onto tin-doped indium oxide substrate electrodes is employed as a support for liquid|liquid redox systems. The system 1-decyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide|aqueous electrolyte is studied with t-butylferrocene as an electrochemically active component in the ionic liquid phase. Redox processes within the ionic liquid are coupled to ion transfer processes at the ionic liquid|water interface. The carbon nanofiber electrode material provides an ideal porous support and allows both high Faradaic and high capacitive currents to be achieved. The capacitive current obtained after immobilisation of 1-decyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide and immersion into aqueous electrolyte indicates that most (ca 65%) of the real carbon nanofiber surface is active, electrically connected to the substrate electrode, and in direct contact with the ionic liquid. The reversible oxidation and re-reduction of t-butylferrocene in 1-decyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide occurs at a potential which depends on the composition and nature of the aqueous electrolyte as well as on the type of electrode. The position of differential pulse voltammetric oxidation peak potentials is shown to depend on the type of anion present in the aqueous solution phase with most significant effects for the hydrophobic ClO4- and PF6- anions. Although only the Faradaic voltammetric response allows the ion transfer mechanism to be analysed, anion transfer is proposed to be coupled to both Faradaic and capacitive charge transfer." @default.
• W2032920135 created "2016-06-24" @default.
• W2032920135 creator A5016443120 @default.
• W2032920135 creator A5033435814 @default.
• W2032920135 creator A5043153528 @default.
• W2032920135 creator A5054132422 @default.
• W2032920135 creator A5071095075 @default.
• W2032920135 creator A5080938854 @default.
• W2032920135 creator A5088859796 @default.
• W2032920135 date "2006-02-01" @default.
• W2032920135 modified "2023-09-24" @default.
• W2032920135 title "Ion transfer processes at the room temperature ionic liquid|aqueous solution interface supported by a hydrophobic carbon nanofibers – silica composite film" @default.
• W2032920135 cites W1823294799 @default.
• W2032920135 cites W191442324 @default.
• W2032920135 cites W1933332461 @default.
• W2032920135 cites W1968329089 @default.
• W2032920135 cites W1970540061 @default.
• W2032920135 cites W1971975202 @default.
• W2032920135 cites W1976274969 @default.
• W2032920135 cites W1978121735 @default.
• W2032920135 cites W1987251735 @default.
• W2032920135 cites W1988724611 @default.
• W2032920135 cites W1996215310 @default.
• W2032920135 cites W2000476195 @default.
• W2032920135 cites W2002563284 @default.
• W2032920135 cites W2002799227 @default.
• W2032920135 cites W2005637740 @default.
• W2032920135 cites W2012444319 @default.
• W2032920135 cites W2015807269 @default.
• W2032920135 cites W2020981060 @default.
• W2032920135 cites W2023554843 @default.
• W2032920135 cites W2030307040 @default.
• W2032920135 cites W2030960286 @default.
• W2032920135 cites W2035002017 @default.
• W2032920135 cites W2037085649 @default.
• W2032920135 cites W2038534169 @default.
• W2032920135 cites W2039959013 @default.
• W2032920135 cites W2040615561 @default.
• W2032920135 cites W2054273379 @default.
• W2032920135 cites W2055215830 @default.
• W2032920135 cites W2060932744 @default.
• W2032920135 cites W2062490381 @default.
• W2032920135 cites W2066418147 @default.
• W2032920135 cites W2067410595 @default.
• W2032920135 cites W2069823715 @default.
• W2032920135 cites W2070982845 @default.
• W2032920135 cites W2074910772 @default.
• W2032920135 cites W2075584106 @default.
• W2032920135 cites W2085038435 @default.
• W2032920135 cites W2095089579 @default.
• W2032920135 cites W2098927831 @default.
• W2032920135 cites W2121688293 @default.
• W2032920135 cites W2125207246 @default.
• W2032920135 cites W2126454251 @default.
• W2032920135 cites W2168743201 @default.
• W2032920135 cites W2785503657 @default.
• W2032920135 doi "https://doi.org/10.1016/j.jelechem.2005.11.002" @default.
• W2032920135 hasPublicationYear "2006" @default.
• W2032920135 type Work @default.
• W2032920135 sameAs 2032920135 @default.
• W2032920135 citedByCount "36" @default.
• W2032920135 countsByYear W20329201352012 @default.
• W2032920135 countsByYear W20329201352013 @default.
• W2032920135 countsByYear W20329201352019 @default.
• W2032920135 countsByYear W20329201352020 @default.
• W2032920135 countsByYear W20329201352023 @default.
• W2032920135 crossrefType "journal-article" @default.
• W2032920135 hasAuthorship W2032920135A5016443120 @default.
• W2032920135 hasAuthorship W2032920135A5033435814 @default.
• W2032920135 hasAuthorship W2032920135A5043153528 @default.
• W2032920135 hasAuthorship W2032920135A5054132422 @default.
• W2032920135 hasAuthorship W2032920135A5071095075 @default.
• W2032920135 hasAuthorship W2032920135A5080938854 @default.
• W2032920135 hasAuthorship W2032920135A5088859796 @default.
• W2032920135 hasConcept C127413603 @default.
• W2032920135 hasConcept C147789679 @default.
• W2032920135 hasConcept C154881586 @default.
• W2032920135 hasConcept C161790260 @default.
• W2032920135 hasConcept C17525397 @default.
• W2032920135 hasConcept C178790620 @default.
• W2032920135 hasConcept C179104552 @default.
• W2032920135 hasConcept C184651966 @default.
• W2032920135 hasConcept C185592680 @default.
• W2032920135 hasConcept C42360764 @default.
• W2032920135 hasConcept C68801617 @default.
• W2032920135 hasConceptScore W2032920135C127413603 @default.
• W2032920135 hasConceptScore W2032920135C147789679 @default.
• W2032920135 hasConceptScore W2032920135C154881586 @default.
• W2032920135 hasConceptScore W2032920135C161790260 @default.
• W2032920135 hasConceptScore W2032920135C17525397 @default.
• W2032920135 hasConceptScore W2032920135C178790620 @default.
• W2032920135 hasConceptScore W2032920135C179104552 @default.
• W2032920135 hasConceptScore W2032920135C184651966 @default.
• W2032920135 hasConceptScore W2032920135C185592680 @default.
• W2032920135 hasConceptScore W2032920135C42360764 @default.
• W2032920135 hasConceptScore W2032920135C68801617 @default.
• W2032920135 hasIssue "1" @default.
• W2032920135 hasLocation W20329201351 @default.

• next