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- W2032928566 abstract "The rates of hydrogen exchange between tritiated water and α-FeOOH have been measured in the temperature range 36–94°, using a Berthier ratio of 0.01 (which is the ratio of exchangeable atoms in the solid and liquid phases), and found to be independent of pH. The activation energy for self-diffusion and the pre-exponential factor Do of the self-diffusion coefficient were calculated from the initial parabolic portions of the kinetic curves as 8.2±1.3 kcal mole–1 and 6.5 × 10–13 cm2 respectively. A mechanism involving hydrogen-bond rupture and rotation of a defect water molecule within the solid is proposed. The anisotropic diffusion coefficients implied by such a mechanism are calculated." @default.
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- W2032928566 date "1968-01-01" @default.
- W2032928566 modified "2023-09-23" @default.
- W2032928566 title "Proton transfer studies in the ferric oxyhydroxides. Part 1.—Hydrogen exchange between α-FeOOH and water" @default.
- W2032928566 doi "https://doi.org/10.1039/tf9686400785" @default.
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