FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2032960249> ?p ?o ?g. }

• W2032960249 endingPage "2214" @default.
• W2032960249 startingPage "2207" @default.
• W2032960249 abstract "Treatment of [PtCl2(L–L)][L–L = 2 PPh3, Ph2PCH2PPh2(dppm) or Fe(C5H4PPh2)2(dppf)] with Ag(O2CR)(R = Me, CF3, Pri or Ph) at room temperature generally gave [Pt(O2CR)2(L–L)] in moderate to good yields. The crystal and molecular structures of [Pt(O2CMe)2(dppf)]·H2O, [Pt(O2CPh)2(dppf)]·CH2Cl2 and [Pt(O2CCF3)2(dppm)] have been determined by single-crystal X-ray diffractometry. All these complexes show a mononuclear square-planar structure with a chelating diphosphine and two neighbouring (cis) carboxylates in a monodentate mode. These structures contrast those of the parent [Pt4(µ-O2CMe)8] and its derivative [Pt4(en)4(µ-O2CMe)4]4+(en = ethylenediamine) which are tetrameric, based on octahedral PtII, and contain bridging acetates and direct Pt–Pt bonds. Fenske–Hall molecular orbital calculations of these structures confirmed the existence of Pt–Pt bonding interactions. The presence of hard and electronegative ligands like en and acetate incurs a deficiency in σ-electron density, compared to virtually filled non-bonding orbitals; the former is alleviated by Pt–Pt bonding. d8 Complexes with ligands like phosphines possessing both σ-donating and π-accepting qualities appear to favour the usual square-planar geometry." @default.
• W2032960249 created "2016-06-24" @default.
• W2032960249 creator A5003336128 @default.
• W2032960249 creator A5003853840 @default.
• W2032960249 creator A5011142645 @default.
• W2032960249 creator A5025981159 @default.
• W2032960249 creator A5029935613 @default.
• W2032960249 creator A5051926752 @default.
• W2032960249 creator A5085275319 @default.
• W2032960249 date "1996-01-01" @default.
• W2032960249 modified "2023-09-30" @default.
• W2032960249 title "Bis(carboxylato) complexes of platinum(<scp>II</scp>). Structural and bonding analysis of [Pt(O₂CR)₂(L–L)][L–L = 2PPh₃, Ph₂PCH₂PPh₂or Fe(C₅H₄PPh₂)₂; R = Me, CF₃, Prⁱor Ph]" @default.
• W2032960249 cites W1582010653 @default.
• W2032960249 cites W1968392598 @default.
• W2032960249 cites W1970234358 @default.
• W2032960249 cites W1978059942 @default.
• W2032960249 cites W1979990023 @default.
• W2032960249 cites W1981453282 @default.
• W2032960249 cites W1981500123 @default.
• W2032960249 cites W1984879579 @default.
• W2032960249 cites W1985488693 @default.
• W2032960249 cites W1995529355 @default.
• W2032960249 cites W1999762863 @default.
• W2032960249 cites W2007630413 @default.
• W2032960249 cites W2009202316 @default.
• W2032960249 cites W2010332779 @default.
• W2032960249 cites W2020906830 @default.
• W2032960249 cites W2022869480 @default.
• W2032960249 cites W2023429264 @default.
• W2032960249 cites W2024122111 @default.
• W2032960249 cites W2024701156 @default.
• W2032960249 cites W2032912803 @default.
• W2032960249 cites W2033336148 @default.
• W2032960249 cites W2037335026 @default.
• W2032960249 cites W2038202942 @default.
• W2032960249 cites W2041603559 @default.
• W2032960249 cites W2049249545 @default.
• W2032960249 cites W2054620335 @default.
• W2032960249 cites W2055518161 @default.
• W2032960249 cites W2057820145 @default.
• W2032960249 cites W2059734582 @default.
• W2032960249 cites W2061496821 @default.
• W2032960249 cites W2061899402 @default.
• W2032960249 cites W2065096317 @default.
• W2032960249 cites W2065303164 @default.
• W2032960249 cites W2067300958 @default.
• W2032960249 cites W2074539671 @default.
• W2032960249 cites W2083024717 @default.
• W2032960249 cites W2084817502 @default.
• W2032960249 cites W2084853974 @default.
• W2032960249 cites W2085267599 @default.
• W2032960249 cites W2099541283 @default.
• W2032960249 cites W2135999763 @default.
• W2032960249 cites W2160423347 @default.
• W2032960249 cites W2170927443 @default.
• W2032960249 cites W2949402086 @default.
• W2032960249 cites W2952679727 @default.
• W2032960249 cites W3021515054 @default.
• W2032960249 cites W3042689588 @default.
• W2032960249 cites W3139312188 @default.
• W2032960249 doi "https://doi.org/10.1039/dt9960002207" @default.
• W2032960249 hasPublicationYear "1996" @default.
• W2032960249 type Work @default.
• W2032960249 sameAs 2032960249 @default.
• W2032960249 citedByCount "22" @default.
• W2032960249 countsByYear W20329602492013 @default.
• W2032960249 countsByYear W20329602492018 @default.
• W2032960249 countsByYear W20329602492023 @default.
• W2032960249 crossrefType "journal-article" @default.
• W2032960249 hasAuthorship W2032960249A5003336128 @default.
• W2032960249 hasAuthorship W2032960249A5003853840 @default.
• W2032960249 hasAuthorship W2032960249A5011142645 @default.
• W2032960249 hasAuthorship W2032960249A5025981159 @default.
• W2032960249 hasAuthorship W2032960249A5029935613 @default.
• W2032960249 hasAuthorship W2032960249A5051926752 @default.
• W2032960249 hasAuthorship W2032960249A5085275319 @default.
• W2032960249 hasConcept C161790260 @default.
• W2032960249 hasConcept C185592680 @default.
• W2032960249 hasConcept C518104683 @default.
• W2032960249 hasConcept C55493867 @default.
• W2032960249 hasConcept C71240020 @default.
• W2032960249 hasConcept C8010536 @default.
• W2032960249 hasConceptScore W2032960249C161790260 @default.
• W2032960249 hasConceptScore W2032960249C185592680 @default.
• W2032960249 hasConceptScore W2032960249C518104683 @default.
• W2032960249 hasConceptScore W2032960249C55493867 @default.
• W2032960249 hasConceptScore W2032960249C71240020 @default.
• W2032960249 hasConceptScore W2032960249C8010536 @default.
• W2032960249 hasIssue "11" @default.
• W2032960249 hasLocation W20329602491 @default.
• W2032960249 hasOpenAccess W2032960249 @default.
• W2032960249 hasPrimaryLocation W20329602491 @default.
• W2032960249 hasRelatedWork W1992410727 @default.
• W2032960249 hasRelatedWork W2003242108 @default.
• W2032960249 hasRelatedWork W2030410536 @default.
• W2032960249 hasRelatedWork W2038725059 @default.
• W2032960249 hasRelatedWork W2080869919 @default.
• W2032960249 hasRelatedWork W2089961873 @default.

• next