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- W2032972805 abstract "Three optically active phosphanes ([(S)-2-methylbutyl]3−nP[phenyl]n(n = 0, 1, 2), were tested as ligands in rhodium(I) complexes to form catalysts for the enantioselective dimerisation of (R)- and (S)-oct-1-yn-3-ol. The catalytic reaction provides enantioselectivity for this type of CC bond formation. For reactions at 45–75°C and depending on the P-ligand used the rates vary for both enantiomers from 6:1 to 50:1 in favour of the (S)-octynol. Drei optisch aktive Phosphane [(S)-2-Methylbutyl]3−nP[phenyl]n (n = 0, 1, 2), wurden als Liganden in Rhodium(I)-Komplexen eingesetzt, um eine enantioselektive Dimerisierung von (R)- und (S)-Oct-1-in-3-ol zu erreichen. Die untersuchte Reaktion ergibt eine Enantioselektivität für diese Art der CC Verknüpfung. Für Reaktionen von 45–75°C und abhängig vom eingesetzten P-Liganden differieren die Umsetzungsgeschwindigkeiten für beide Enantiomeren von 6 : 1 bis 50 : 1 zugunsten des (S)-Octinols." @default.
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- W2032972805 date "1996-02-01" @default.
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- W2032972805 title "Vergleichende dimerisierung der enantiomere von Oct-1-in-3-ol mit chiralen rhodium-phosphan-komplexen" @default.
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- W2032972805 doi "https://doi.org/10.1016/0022-328x(95)05845-g" @default.
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