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- W2032977603 abstract "The origin of the carbon skeleton of verrucarin E (1) from acetate as precursor is confirmed. Incorporation studies with [1,2-13C]-acetate have demonstrated that two acetoacetate units couple together as shown in pattern A (Scheme 2) and not as in B. Analysis of the deuterium distribution in both verrucarin E (1) isolated after the incorporation of [2-13C,2-2H3]-acetate and in sodium acetate obtained after Kuhn-Roth oxidation of the metabolite demonstrated that C(7) is derived from the starter unit of one of the acetoacetate moieties. The deuterium exchange in verrucarin E (1) occurring during fermentation was investigated." @default.
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- W2032977603 date "1980-06-06" @default.
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- W2032977603 title "Biosynthesis of the antibiotic verrucarin E use of [1-13C]-, [2-13C]-, [1,2-13C]- and [2-13C, 2-2H3]-acetates. Verrucarins and roridins, 37th communication [1]" @default.
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- W2032977603 doi "https://doi.org/10.1002/hlca.19800630402" @default.
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