FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2032978173> ?p ?o ?g. }

• W2032978173 endingPage "453" @default.
• W2032978173 startingPage "443" @default.
• W2032978173 abstract "A new asymmetrically coordinated bis-trinuclear iron(III) cluster containing a [Fe(3)O](7+) core has been synthesized and structurally, magnetically, and spectroscopically characterized. [Fe(6)Na(2)O(2)(O(2)CPh)(10)(pic)(4)(EtOH)(4)(H(2)O)(2)](ClO(4))(2).2EpsilontOH (1.2EpsilontOH) crystallizes in the P space group and consists of two symmetry-related {Fe(3)O](7+) subunits linked by two Na(+) cations. Inside each [Fe(3)O](7+) subunit, the iron(III) ions are antiferromagnetically coupled, and their magnetic exchange is best described by an isosceles triangle model with two equal (J) and one different (J ') coupling constants. On the basis of the H = -2SigmaJ(ij)S(i)S(j) spin Hamiltonian formalism, the two best fits to the data yield solutions J = -27.4 cm(-1), J ' = -20.9 cm(-1) and J = -22.7 cm(-1), J ' = -31.6 cm(-1). The ground state of the cluster is S = (1)/(2). X-band electron paramagnetic resonance (EPR) spectroscopy at liquid-helium temperature reveals a signal comprising a sharp peak at g approximately 2 and a broad tail at higher magnetic fields consistent with the S = (1)/(2) character of the ground state. Variable-temperature zero-field and magnetically perturbed Mössbauer spectra at liquid-helium temperatures are consistent with three antiferromagnetically coupled high-spin ferric ions in agreement with the magnetic susceptibility and EPR results. The EPR and Mössbauer spectra are interpreted by assuming the presence of an antisymmetric exchange interaction with |d| approximately 2-4 cm(-1) and a distribution of exchange constants J(ij)." @default.
• W2032978173 created "2016-06-24" @default.
• W2032978173 creator A5005648652 @default.
• W2032978173 creator A5020055544 @default.
• W2032978173 creator A5023289483 @default.
• W2032978173 creator A5044379923 @default.
• W2032978173 creator A5082964773 @default.
• W2032978173 date "2005-12-09" @default.
• W2032978173 modified "2023-10-13" @default.
• W2032978173 title "An Octanuclear Complex Containing the {Fe₃O}⁷⁺ Metal Core: Structural, Magnetic, Mössbauer, and Electron Paramagnetic Resonance Studies" @default.
• W2032978173 cites W1152544408 @default.
• W2032978173 cites W1623176633 @default.
• W2032978173 cites W1632501685 @default.
• W2032978173 cites W172663739 @default.
• W2032978173 cites W1965284073 @default.
• W2032978173 cites W1973379485 @default.
• W2032978173 cites W1978216389 @default.
• W2032978173 cites W1983370438 @default.
• W2032978173 cites W1985857032 @default.
• W2032978173 cites W1994056831 @default.
• W2032978173 cites W2006334232 @default.
• W2032978173 cites W2012938835 @default.
• W2032978173 cites W2014938024 @default.
• W2032978173 cites W2015302503 @default.
• W2032978173 cites W2022958435 @default.
• W2032978173 cites W2024509898 @default.
• W2032978173 cites W2033493424 @default.
• W2032978173 cites W2035365817 @default.
• W2032978173 cites W2037391065 @default.
• W2032978173 cites W2039551402 @default.
• W2032978173 cites W2047596931 @default.
• W2032978173 cites W2048743176 @default.
• W2032978173 cites W2055008799 @default.
• W2032978173 cites W2059539984 @default.
• W2032978173 cites W2062837393 @default.
• W2032978173 cites W2062903599 @default.
• W2032978173 cites W2063695143 @default.
• W2032978173 cites W2064893593 @default.
• W2032978173 cites W2070510064 @default.
• W2032978173 cites W2084744164 @default.
• W2032978173 cites W2085819780 @default.
• W2032978173 cites W2087508493 @default.
• W2032978173 cites W2088257105 @default.
• W2032978173 cites W2089622966 @default.
• W2032978173 cites W2132817170 @default.
• W2032978173 cites W2134753771 @default.
• W2032978173 cites W2154864221 @default.
• W2032978173 cites W2157986221 @default.
• W2032978173 cites W2160045920 @default.
• W2032978173 cites W2167643892 @default.
• W2032978173 cites W2172171297 @default.
• W2032978173 doi "https://doi.org/10.1021/ic051652x" @default.
• W2032978173 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16390088" @default.
• W2032978173 hasPublicationYear "2005" @default.
• W2032978173 type Work @default.
• W2032978173 sameAs 2032978173 @default.
• W2032978173 citedByCount "59" @default.
• W2032978173 countsByYear W20329781732012 @default.
• W2032978173 countsByYear W20329781732013 @default.
• W2032978173 countsByYear W20329781732014 @default.
• W2032978173 countsByYear W20329781732015 @default.
• W2032978173 countsByYear W20329781732016 @default.
• W2032978173 countsByYear W20329781732017 @default.
• W2032978173 countsByYear W20329781732018 @default.
• W2032978173 countsByYear W20329781732019 @default.
• W2032978173 countsByYear W20329781732020 @default.
• W2032978173 countsByYear W20329781732021 @default.
• W2032978173 crossrefType "journal-article" @default.
• W2032978173 hasAuthorship W2032978173A5005648652 @default.
• W2032978173 hasAuthorship W2032978173A5020055544 @default.
• W2032978173 hasAuthorship W2032978173A5023289483 @default.
• W2032978173 hasAuthorship W2032978173A5044379923 @default.
• W2032978173 hasAuthorship W2032978173A5082964773 @default.
• W2032978173 hasConcept C113196181 @default.
• W2032978173 hasConcept C121332964 @default.
• W2032978173 hasConcept C124712363 @default.
• W2032978173 hasConcept C131538251 @default.
• W2032978173 hasConcept C155355069 @default.
• W2032978173 hasConcept C184779094 @default.
• W2032978173 hasConcept C185592680 @default.
• W2032978173 hasConcept C187961010 @default.
• W2032978173 hasConcept C26873012 @default.
• W2032978173 hasConcept C43617362 @default.
• W2032978173 hasConcept C46141821 @default.
• W2032978173 hasConcept C69523127 @default.
• W2032978173 hasConcept C70854507 @default.
• W2032978173 hasConcept C8010536 @default.
• W2032978173 hasConceptScore W2032978173C113196181 @default.
• W2032978173 hasConceptScore W2032978173C121332964 @default.
• W2032978173 hasConceptScore W2032978173C124712363 @default.
• W2032978173 hasConceptScore W2032978173C131538251 @default.
• W2032978173 hasConceptScore W2032978173C155355069 @default.
• W2032978173 hasConceptScore W2032978173C184779094 @default.
• W2032978173 hasConceptScore W2032978173C185592680 @default.
• W2032978173 hasConceptScore W2032978173C187961010 @default.
• W2032978173 hasConceptScore W2032978173C26873012 @default.
• W2032978173 hasConceptScore W2032978173C43617362 @default.
• W2032978173 hasConceptScore W2032978173C46141821 @default.

• next