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- W2032979488 abstract "Fluorescence excitation spectra of (COF)2 (à ← [Xtilde]) have been observed in the 32 350–33 150 cm-1 spectral region under various magnetic fields below 10 kG. Fluorescence intensity and decay of (COF)2 vapour have been measured as functions of external magnetic field strength with excitation of the different vibrational bands belonging to the à ← [Xtilde] transition. It is found that fluorescence intensity is reduced considerably by magnetic fields below 1 kG, and the magnetic field quenching is saturated at about 1 kG (the maximum reduction being 43% for the 00 0 band and 69% for the 52 071 1 + 51 081 0 band). The magnetic fluorescence quenching increases with increase in excess vibrational energy and decreases with increase in collision frequency. The fluorescence decay and the fluorescence yield in magnetic fields show that the magnetic quenching of the fluorescence of (COF)2 may be considered by the ‘indirect’ mechanism in a frame of the ‘low’ level density approximation." @default.
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- W2032979488 date "1995-04-10" @default.
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- W2032979488 title "External magnetic field acceleration of radiationless processes in the à state of gaseous oxalyl fluoride" @default.
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- W2032979488 doi "https://doi.org/10.1080/00268979500100641" @default.
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