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- W2032994231 abstract "The traditional interpretation of first-order perturbation theory is investigated by means of the virial theorem, the case of molecular vibrations being used as an example. It is shown that for a potential perturbation, the usual interpretation of first-order theory wrongly partitions the kinetic and potential energies, while for a kinetic perturbation it does not correctly give the first-order energy change." @default.
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- W2032994231 title "The virial theorem and first-order perturbation theory" @default.
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- W2032994231 doi "https://doi.org/10.1088/0022-3719/3/1/004" @default.
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