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- W2033014322 abstract "It was found that 3-acetylpyridine is capable of displacing triphenylphosphine from [CuCl(PPh 3 ) 3 ], forming the title compound, [CuCl(C 7 H 7 NO)(C 18 H 15 P) 2 ]. The two triphenylphosphine ligands possess the same sense of chirality, and the molecules are therefore conformationally chiral. The compound was found to crystallize as a racemate (centrosymmetric space group) under the crystallization conditions employed. The molecular structure shows that the carbonyl C atom is blocked at one side by a triphenylphosphine ligand, while the other face is open for nucleophilic attack. Obtaining chiral crystals of the title compound is thus a future objective. In the crystal structure, C—H...O(=C)-bonded dimers are formed, which are further stabilized by π–π interactions. The dimers form infinite chains through weak C—H...π interactions." @default.
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- W2033014322 date "2006-06-16" @default.
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- W2033014322 title "(3-Acetylpyridine-κ<i>N</i>)chlorobis(triphenylphosphine-κ<i>P</i>)copper(I): a suitable candidate for absolute asymmetric synthesis?" @default.
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- W2033014322 doi "https://doi.org/10.1107/s1600536806021714" @default.
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