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• W2033016667 endingPage "36" @default.
• W2033016667 startingPage "27" @default.
• W2033016667 abstract "Reactions of laser-ablated Y and La atoms with water molecules have been studied using matrix-isolation FTIR spectroscopy and density functional calculations. The reaction products were identified based on isotope labeled experiments and density functional calculations. For both Y and La atom reactions with H2O, the major reaction products are the HMOH, MO and M(OH)2 (M=Y and La) molecules. In addition, HMO and HM(OH)2 were produced on matrix sample annealing or UV broadband photolysis. Evidence is also presented for the formation of the HYOH+ species. The potential energy surfaces for the Y, La+H2O reactions have been calculated to interpret the reaction mechanisms." @default.
• W2033016667 created "2016-06-24" @default.
• W2033016667 creator A5040548876 @default.
• W2033016667 creator A5046362125 @default.
• W2033016667 creator A5079832394 @default.
• W2033016667 date "2001-10-01" @default.
• W2033016667 modified "2023-09-30" @default.
• W2033016667 title "Reactions of laser-ablated Y and La atoms with H2O Infrared spectra and density functional calculations of the HMO, HMOH and M(OH)2 molecules in solid argon" @default.
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• W2033016667 doi "https://doi.org/10.1016/s0301-0104(01)00450-5" @default.
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