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- W2033074586 abstract "The dynamic response of a Sb5+ ion-selective electrode based on 1,2,4,6-tetraphenylpyridinium hexachloroantimonate(V) to different ions, ClO−4, HgCl3−3, AuCl−4,TlCl−4, SbCl−6 and tetraphenylborate, in a flow-injection analysis system using a flow-through cell, is studied. The transient signals obtained are different for every ion. A parameter called relative return rate, defined as the ratio of the return rate to peak height, was found to be characteristic for each ion. It was constant up to a concentration range of three decades for those ions with selectivity coefficients Kpotsb,j ⪡ 1, thus providing a new source of analytical selectivity. Flow injection variables were studied in order to ascertain their influence on this new parameter." @default.
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- W2033074586 date "1994-04-01" @default.
- W2033074586 modified "2023-10-18" @default.
- W2033074586 title "Transient signals with an Antimony(V) ion-selective electrode: The relative signal return rate as a selectivity parameter" @default.
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- W2033074586 doi "https://doi.org/10.1016/0039-9140(93)e0016-7" @default.
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