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- W2033083133 abstract "In contrast to conventional activation of Nu–SiR3 reagents by F ion attributed to the strong affinity of Si to F, S–Si activation can now be achieved using Cl/Br ions of TBAX as catalysts via formation of weaker X–Si bonds and Me3Si–X. This led to a waste-free synthesis of unsymmetrical thioethers via F-free SNAr reactions of activated (hetero)aryl halides and RS–SiMe3, with recovery of the useful Me3Si–X reagent in high yields." @default.
- W2033083133 created "2016-06-24" @default.
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- W2033083133 date "2014-01-01" @default.
- W2033083133 modified "2023-10-12" @default.
- W2033083133 title "Sulfur–silicon bond activation catalysed by Cl/Br ions: waste-free synthesis of unsymmetrical thioethers by replacing fluoride catalysis and fluorinated substrates in SNAr reactions" @default.
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- W2033083133 doi "https://doi.org/10.1039/c4gc00535j" @default.
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