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- W2033089366 abstract "Abstract Treatment of RCH(OMEM)CFBr2 with n-BuLi at −130 °C in the presence of 4-heptanone gives the corresponding adduct diastereoselectively. The stereochemical outcome is explained in terms of the chelation between lithium and oxygen atoms of the MEM group. Starting with 2-phenylpropanal, a product is produced highly selectively containing three contiguous stereocenters including a -CFBr- moiety." @default.
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- W2033089366 date "1996-10-01" @default.
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- W2033089366 title "Diastereoselective generation of lithium carbenoid reagent RCH(OMEM)CFBrLi and its reaction with electrophiles" @default.
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- W2033089366 doi "https://doi.org/10.1016/0040-4039(96)01684-x" @default.
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