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- W2033097696 abstract "A mixture of [Ni(Et-sal)2] (= bis(N-ethylsalicylaldiminato)nickel(II)) and [Fe(Ox)3]3− (tris-(oxalato)fcrrate(III) ion) displays longwavelength absorption at λmax=472 nm. This new absorption band is assigned to an outer-sphere LMCT transition from the coordinated ethylsalicylaldimine of [Ni(Et-sal)2] to Fe(III) of [Fe(Ox)3]3−. Mixing free ethylsalicyldimine or [M(Et-sal)2] (where M = Co(II), Cu(II) or Zn(II)) and [Fe(Ox)3]3− also shows the same phenomenon; the maximum of the new absorption band is independent on the nature of the metal." @default.
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- W2033097696 date "1990-10-01" @default.
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- W2033097696 title "Optical outer-sphere ligand to metal charge transfer in bis(N-ethylsalicylaldiminato)nickel(II)/tris(oxalato)ferrate(III)" @default.
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- W2033097696 doi "https://doi.org/10.1016/s0020-1693(00)84857-4" @default.
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