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- W2033100178 abstract "Abstract The first equilibrium constant for the combination of ligand with cupric ion, K1, is related to the half-complexation potential, EHC, by log K1 = a + b[EHC]. The coefficients differ for n ⩽ 2 and n ⩾ 2, where n is the number of nitrogen atoms in the molecule. The correlation coefficients, r, based on data available from the literature were −0.98. The equations can be used for estimating log K1 of aliphatic amines. Successful titration of aliphatic amines vs cupric ion requires log K1 ⩾ 4 and an initial pH of a 10−3 M solution of ⩾9." @default.
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- W2033100178 date "1982-06-01" @default.
- W2033100178 modified "2023-09-25" @default.
- W2033100178 title "Microdetermination of aliphatic amines and polyamines with cupric ion: Relationship between pK1 and half-complexation potential" @default.
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- W2033100178 doi "https://doi.org/10.1016/0026-265x(82)90109-6" @default.
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