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• W2033204416 abstract "High resolution (<0.2 eV) sulphur L-edge X-ray absorption near-edge structure (XANES) spectra of several model organic and inorganic sulphur compounds have been recorded using monochromatized synchrotron radiation. The near-edge features in the sulphur L-edge spectra are much more sensitive to the sulphur chemical environments than any previously reported spectroscopic technique (e.g. X-ray photoelectron spectrometry or sulphur K-edge XANES). The sulphur L-edge spectra of the model compounds have been used as a fingerprint to identify the inorganic and, in particular, the organic forms of sulphur in Rasa coal. The results indicate that 70% of the organic form in Rasa coal is of thiophenic origin and 30% is of aryl sulphide origin. No detectable quantities (≈ 1 wt%) of pyrite or oxidized forms of sulphur were found in this coal." @default.
• W2033204416 created "2016-06-24" @default.
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• W2033204416 date "1992-06-01" @default.
• W2033204416 modified "2023-09-25" @default.
• W2033204416 title "Direct identification of organic sulphur species in Rasa coal from sulphur L-edge X-ray absorption near-edge spectra" @default.
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• W2033204416 doi "https://doi.org/10.1016/0016-2361(92)90167-m" @default.
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