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• W2033290895 abstract "In photorefractive Pb5Ge3O11 and (Pb0.98Ba0.02)5Ge3O11 crystals, Pb2+ host lattice ions can be recharged by visible light to Pb3+. The magnetic and structural properties of this hole-trapping centre, metastable at low temperatures, are characterized by means of electron paramagnetic resonance. The axial g-parameters are found to be g⊥ = 2.0005(4) and g∥ = g⊥ + 0.0064(3) and the 207Pb hyperfine interaction constants are A⊥ = 34.77(5) and A∥ = 34.64(5) GHz. This information is correlated with optical properties derived from optically detected magnetic resonance via the magnetic circular dichroism of the absorption. In this way, broad photochromic absorption bands extending from the band edge to 1.9 eV can be attributed to the Pb3+ centre. Several observations give evidence that the Pb3+ centre is involved in the holographic recharging effects observed in lead germanate." @default.
• W2033290895 created "2016-06-24" @default.
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• W2033290895 date "2001-04-05" @default.
• W2033290895 modified "2023-09-23" @default.
• W2033290895 title "Photoactive Pb³⁺host lattice ions in photorefractive Pb₅Ge₃O₁₁investigated by magnetic resonance techniques" @default.
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• W2033290895 doi "https://doi.org/10.1088/0953-8984/13/16/307" @default.
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