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- W2033333744 abstract "Abstract The reaction of (I)‐1‐fluoro‐1‐methyl‐2,2‐diphenylcyclopropane ( 1 ) with lithium metal produced a variety of ring‐opened, as well as cyclopropane, products. Initial electron transfer from the lithium metal surface to 1 is to the phenyl ring of 1 rather than to the carbon‐fluorine bond. Using chiral 1 , the 1‐lithio‐1‐methyl‐2,2‐diphenylcyclopropane produced yielded, upon carbonation, the corresponding acid which was largely racemized. The mechanism of the electron transfer reaction is discussed." @default.
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- W2033333744 date "1981-01-01" @default.
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- W2033333744 title "Cyclopropanes. XLI. Electron Transfer from Lithium Metal Surfaces to (±) and (−)-(<i>S</i>)-1-Fluoro-1-methyl-2,2-diphenylcyclopropane" @default.
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- W2033333744 doi "https://doi.org/10.1002/ijch.198100041" @default.
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